CAS 110-95-2|TMPDA

Introduction:Basic information about CAS 110-95-2|TMPDA, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NameTMPDA
CAS Number110-95-2Molecular Weight130.231
Density0.8±0.1 g/cm3Boiling Point143.3±8.0 °C at 760 mmHg
Molecular FormulaC7H18N2Melting Point/
MSDSUSAFlash Point31.7±0.0 °C
Symbol
GHS02, GHS05, GHS06
Signal WordDanger

Names

NameN,N,N',N'-Tetramethyl-1,3-propanediamine
SynonymMore Synonyms

Chemical & Physical Properties

Density0.8±0.1 g/cm3
Boiling Point143.3±8.0 °C at 760 mmHg
Molecular FormulaC7H18N2
Molecular Weight130.231
Flash Point31.7±0.0 °C
Exact Mass130.147003
PSA6.48000
LogP0.43
Vapour Pressure5.4±0.3 mmHg at 25°C
Index of Refraction1.442
InChIKeyDMQSHEKGGUOYJS-UHFFFAOYSA-N
SMILESCN(C)CCCN(C)C
Storage conditionFlammables area
StabilityStable. Flammable. Incompatible with strong oxidizing agents, acids, acid chlorides, permanganates, carbon dioxide, nitrates, peroxides, nitrites, halogens.

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TX8400000
CHEMICAL NAME :
1,3-Propanediamine, N,N,N',N'-tetramethyl-
CAS REGISTRY NUMBER :
110-95-2
BEILSTEIN REFERENCE NO. :
1734176
LAST UPDATED :
199801
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C7-H18-N2
MOLECULAR WEIGHT :
130.27
WISWESSER LINE NOTATION :
1N1&3N1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
410 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
375 ppm/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
WADTAA Wright Air Development Center, Technical Report, U.S. Air Force. (Wright-Patterson Air Force Base, OH 45433) Volume(issue)/page/year: 55-250,10,1955
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
300 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
>316 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 6,149,1982 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
12 ppm/6H/30D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cough
REFERENCE :
WADTAA Wright Air Development Center, Technical Report, U.S. Air Force. (Wright-Patterson Air Force Base, OH 45433) Volume(issue)/page/year: 55-250,10,1955
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
12 ppm/6H/30D-I
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified
REFERENCE :
WADTAA Wright Air Development Center, Technical Report, U.S. Air Force. (Wright-Patterson Air Force Base, OH 45433) Volume(issue)/page/year: 55-250,10,1955

Safety Information

Symbol
GHS02, GHS05, GHS06
Signal WordDanger
Hazard StatementsH226-H302-H311-H314
Precautionary StatementsP280-P305 + P351 + P338-P310
Personal Protective EquipmentFaceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard CodesT:Toxic;
Risk PhrasesR10;R22;R24;R34
Safety PhrasesS16-S26-S36/37/39-S45-S24/25
RIDADRUN 2734 8/PG 2
WGK Germany2
RTECSTX8400000
Packaging GroupIII
Hazard Class3
HS Code2921290000

Customs

HS Code2921290000
Summary2921290000 other acyclic polyamines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles4

More Articles
N,N,N',N'-Tetramethyl-1,3-propanediamine as the catalyst of choice for the Baylis-Hillman reaction of cycloalkenone: rate acceleration by stabilizing the zwitterionic intermediate via the ion-dipole interaction. Lee KY, et al.

Tetrahedron Lett. 45(28) , 5485-5488, (2004)

Synthesis of homodimeric monomethine cyanine dyes as noncovalent nucleic acid labels and their absorption and fluorescence spectral characteristics. Deligeorgiev TG, et al.

Dyes and Pigments 44(2) , 131-136, (2000)

Synthesis, physical properties, and structural characterization of. mu.-carbonato-dichlorobis (N,N,N',N'-Tetramethyl-1,3-propanediamine) dicopper(II), LCuCl(CO3)ClCuL, a diamagnetic initiator for the oxidative coupling of phenols by dioxygen. Churchill MR, et al.

Inorg. Chem. 18(8) , 2296-2300, (1979)

Synonyms

bis[(dimethylamino)methyl]methane
N,N,N′,N′-Tetramethyl-1,3-propanediamine
N,N,N',N'-Tetramethylpropane-1,3-diamine
1,3-Propanediamine, N,N,N,N-tetramethyl-
N1,N1,N3,N3-Tetramethylpropane-1,3-diamine
Tetramethyl-1,3-diaminopropane
MFCD00008337
1,3-Bis(dimethylamino)propane
N,N,N',N'-Tetramethyltrimethylenediamine
N,N,N‘,N‘-Tetramethyl-1,3-propanediamine
TMPDA
N,N,N',N'-Tetramethyl-1,3-propanediamine
N,N,N',N'-TetraMethyl-1,3-diaMinopropane
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