CAS 1184-78-7|Trimethylamine oxide

Introduction:Basic information about CAS 1184-78-7|Trimethylamine oxide, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NameTrimethylamine oxide
CAS Number1184-78-7Molecular Weight75.110
Density0.9301 (rough estimate)Boiling Point133.8°C (rough estimate)
Molecular FormulaC3H9NOMelting Point220-222ºC(lit.)
MSDSChineseUSAFlash Point/
Symbol
GHS07
Signal WordWarning

Names

Nametrimethylamine N-oxide
SynonymMore Synonyms

Trimethylamine oxide BiologicalActivity

DescriptionTrimethylamine N-oxide is a gut microbe-dependent metabolite of dietary choline and other trimethylamine-containing nutrients. Trimethylamine N-oxide induces inflammation by activating the ROS/NLRP3 inflammasome. Trimethylamine N-oxide also accelerates fibroblast-myofibroblast differentiation and induces cardiac fibrosis by activating the TGF-β/smad2 signaling pathway[1][2][3].
Related CatalogSignaling Pathways >>Stem Cell/Wnt >>TGF-beta/SmadResearch Areas >>Cardiovascular DiseaseSignaling Pathways >>TGF-beta/Smad >>TGF-beta/SmadSignaling Pathways >>Immunology/Inflammation >>NOD-like Receptor (NLR)Research Areas >>Inflammation/Immunology
Target

ROS/NLRP3 inflammasome[1] TGF-β/smad2[1]

In VitroThe size and migration of fibroblasts are increased after Trimethylamine N-oxide (TMAO) treatment compared with non-treated fibroblasts in vitro. Trimethylamine N-oxide increases TGF-β receptor I expression, which promotes the phosphorylation of Smad2 and up-regulates the expression of α-SMA and collagen I. The ubiquitination of TGF-βRI is decreased in neonatal mouse fibroblasts after Trimethylamine N-oxide treatment. Trimethylamine N-oxide also inhibits the expression of smurf2[2]. Trimethylamine N-oxide is frequently found in the tissues of a variety of marine organisms that protects against the adverse effects of temperature, salinity, high urea and hydrostatic pressure[3].
In VivoTrimethylamine N-oxide (TMAO) contributes to cardiovascular diseases by promoting inflammatory responses. C57BL/6 mice are fed a normal diet, high-choline diet and/or 3-dimethyl-1-butanol (DMB) diet. The levels of Trimethylamine N-oxide and choline are increased in choline-fed mice. Left ventricular hypertrophy, pulmonary congestion, and diastolic dysfunction are markedly exacerbated in heart failure with preserved ejection fraction (HFpEF) mice fed high-choline diets compared with mice fed the control diet. Myocardial fibrosis and inflammation were markedly increased in HFpEF mice fed high-choline diets compared with animals fed the control diet[1].
References

[1]. Wei Shuai, et al. High-choline Diet Exacerbates Cardiac Dysfunction, Fibrosis, and Inflammation in a Mouse Model of Heart Failure With Preserved Ejection Fraction. J Card Fail. 2020 May 14;S1071-9164(19)31802-0.

[2]. Wenlong Yang, et al. Gut Microbe-Derived Metabolite Trimethylamine N-oxide Accelerates Fibroblast-Myofibroblast Differentiation and Induces Cardiac Fibrosis. J Mol Cell Cardiol. 2019 Sep;134:119-130.

[3]. Manuel T Velasquez, et al. Trimethylamine N-Oxide: The Good, the Bad and the Unknown. Toxins (Basel). 2016 Nov 8;8(11):326.

Chemical & Physical Properties

Density0.9301 (rough estimate)
Boiling Point133.8°C (rough estimate)
Melting Point220-222ºC(lit.)
Molecular FormulaC3H9NO
Molecular Weight75.110
Exact Mass75.068413
PSA29.43000
LogP-2.57
Index of Refraction1.4698 (estimate)
InChIKeyUYPYRKYUKCHHIB-UHFFFAOYSA-N
SMILESC[N+](C)(C)[O-]

Safety Information

Symbol
GHS07
Signal WordWarning
Hazard StatementsH315-H319-H335
Precautionary StatementsP261-P305 + P351 + P338
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Gloves
Hazard CodesXi: Irritant;
Risk PhrasesR36/37/38
Safety Phrases26-37/39
RIDADRNONH for all modes of transport
WGK Germany3
HS Code2921110090

Customs

HS Code2921110090
SummaryHS: 2921110090. methylamine, di- or trimethylamine and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:ab(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. general tariff:30.0%

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Synonyms

TMAO
N,N-Dimethylmethanamine N-oxide
EINECS 214-675-6
Amine oxide, trimethyl-
Triox
anhydrous trimethylamine oxide
TriMethylaMine N-Oxide
N,N-dimethylmethanamine oxide
Methanamine,N,N-dimethyl-,N-oxide
trimethylamine-N-oxide
Trimethylamine oxide
Triméthylamine-oxyde
Trimethylamineoxid
MFCD00002048
Trimethyloxamine
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