CAS 147702-15-6|(S)-VAPOL

Introduction：Basic information about CAS 147702-15-6|(S)-VAPOL, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Safety Information
4. Articles3
5. Synonyms

Common Name	(S)-VAPOL
CAS Number	147702-15-6	Molecular Weight	623.566
Density	1.287 g/cm3	Boiling Point	712.173ºC at 760 mmHg
Molecular Formula	C₄₁H₂₈Cl₂O₂	Melting Point	185-191ºC
MSDS	USA	Flash Point	298.408ºC
Symbol	GHS08	Signal Word	Warning

Names

Name	(3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct (S)-VAPOL
Synonym	More Synonyms

Chemical & Physical Properties

Density	1.287 g/cm3
Boiling Point	712.173ºC at 760 mmHg
Melting Point	185-191ºC
Molecular Formula	C₄₁H₂₈Cl₂O₂
Molecular Weight	623.566
Flash Point	298.408ºC
Exact Mass	622.146606
PSA	40.46000
LogP	12.13310
InChIKey	FXFOHEGGSYVOKR-UHFFFAOYSA-N
SMILES	ClCCl.Oc1c(-c2c(-c3ccccc3)cc3ccc4ccccc4c3c2O)c(-c2ccccc2)cc2ccc3ccccc3c12

Safety Information

Symbol	GHS08
Signal Word	Warning
Hazard Statements	H351
Precautionary Statements	P281
Hazard Codes	Xn
Risk Phrases	37/38-40-41
Safety Phrases	26-36/37/39-36/37-24/25-23
RIDADR	NONH for all modes of transport

Articles3

New synthesis of vaulted biaryl ligands via the Snieckus phenol synthesis.

Org. Lett. 7 , 367, (2005)

[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carbo...

Highly enantioselective deracemization of linear and vaulted biaryl ligands.

Org. Lett. 5 , 1813, (2003)

[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ...

Bao. J. et al.

J. Am. Chem. Soc. 118 , 3392, (1996)

Synonyms

[3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, compd. with dichloromethane (1:1)

2,2'-Diphenyl-3,3'-biphenanthrene-4,4'-diol - dichloromethane (1:1)

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