CAS 38218-24-5|indium(iii) isopropoxide

Introduction:Basic information about CAS 38218-24-5|indium(iii) isopropoxide, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Nameindium(iii) isopropoxide
CAS Number38218-24-5Molecular Weight292.07900
Density0.808 g/mL at 25ºCBoiling Point82℃
Molecular FormulaC3H8O.1/3InMelting Point145ºC (dec.)
MSDS/Flash Point10ºC
Symbol
GHS02, GHS07
Signal WordDanger

Names

NameIndium tri(2-propanolate)
SynonymMore Synonyms

indium(iii) isopropoxide BiologicalActivity

DescriptionIndium(III) Isopropoxide is an organo-metallic compound. Indium(III) Isopropoxide uesd as a hydrogen transfer catalyst for conversion of benzylic alcohols into aldehydes or ketones via Oppenauer oxidation. Indium(III) Isopropoxide also can be used as metal precursor[1][2].
Related CatalogResearch Areas >>OthersSignaling Pathways >>Others >>Others
In VitroIndium(III) isopropoxide as an Oppenauer­oxidation catalyst, and the conversion of primary or secondary alcohols into the corresponding aldehydes or ketones was promoted at room temperature using pivalaldehyde as an oxidant[1].
References

[1]. Yohei Ogiwara, et al. Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation. Synthesis. 2016, 48(23): 4143-4148.

[2]. Daniela Caruntu, et al. One-Step Synthesis of Nearly Monodisperse, Variable-Shaped In 2 O 3 Nanocrystals in Long Chain Alcohol Solutions. The Journal of Physical Chemistry C. March 2010, 114(11):4875-4886.

Chemical & Physical Properties

Density0.808 g/mL at 25ºC
Boiling Point82℃
Melting Point145ºC (dec.)
Molecular FormulaC3H8O.1/3In
Molecular Weight292.07900
Flash Point10ºC
Exact Mass292.05300
PSA69.18000
LogP2.47590
Index of Refractionn20/D1.383
InChIKeyOVZUSPADPSOQQN-UHFFFAOYSA-N
SMILESCC(C)[O-].CC(C)[O-].CC(C)[O-].[In+3]
Water SolubilitySoluble in alcohols, ketones and esters.

Safety Information

Symbol
GHS02, GHS07
Signal WordDanger
Hazard StatementsH225-H319-H336
Precautionary StatementsP210-P261-P305 + P351 + P338
Hazard CodesF: Flammable;Xi: Irritant;
Risk Phrases36/37/38-41-11
Safety Phrases26-36/37/39-36-33-16
RIDADRUN 1219 3/PG 2

Articles2

More Articles
Ambient pressure syntheses of size-controlled corundum-type In2O3 nanocubes.

J. Am. Chem. Soc. 29th ed., 128 , 9326, (2006)

Hydrolysis of In(O-iPr)3 by 10 molar excess of water at 90 degrees C in a surfactant/solvent mixture of oleylamine/oleic acid/trioctylamine provides very small nanoparticles (<5 nm in diameter) of In(...

Caruntu, D.; et al.

J. Phys. Chem. C Nanomater. Interfaces 11th ed., 114 , 4875, (2010)

Synonyms

MFCD00210318
CAS 30686-73-8|4-(2-METHYL-4-THIAZOLYL)PHENOL*
CAS 25169-05-5|Pentakis(diethylamino)niobium(V), 99.9 (Metals basis), Mixture of complexes
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