CAS 1295-35-8|1,2,5,6-cyclooctanetetraylidene, nickel salt

Introduction：Basic information about CAS 1295-35-8|1,2,5,6-cyclooctanetetraylidene, nickel salt, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Toxicological Information
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
MUTATION DATA
4. Safety Information
5. Articles5
6. Synonyms

Common Name	1,2,5,6-cyclooctanetetraylidene, nickel salt
CAS Number	1295-35-8	Molecular Weight	266.992
Density	/	Boiling Point	153.5ºC at 760 mmHg
Molecular Formula	C₁₆H₂₄Ni	Melting Point	60 °C (dec.)(lit.)
MSDS	ChineseUSA	Flash Point	31.7ºC
Symbol	GHS02, GHS08	Signal Word	Danger

Names

Name	Bis(1,5-cyclooctadiene)nickel(0)
Synonym	More Synonyms

Chemical & Physical Properties

Boiling Point	153.5ºC at 760 mmHg
Melting Point	60 °C (dec.)(lit.)
Molecular Formula	C₁₆H₂₄Ni
Molecular Weight	266.992
Flash Point	31.7ºC
Exact Mass	266.060547
LogP	5.34560
Vapour Pressure	4.25mmHg at 25°C
InChIKey	JRTIUDXYIUKIIE-REBFVTMGSA-N
SMILES	C1=CCCC=CCC1.C1=CCCC=CCC1.[Ni]
Storage condition	0-6°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QR6135000

CHEMICAL NAME :: Nickel, bis(1,5-cyclooctadiene)-

CAS REGISTRY NUMBER :: 1295-35-8

LAST UPDATED :: 199410

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C16-H24-Ni

MOLECULAR WEIGHT :: 275.11

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 1 mg/plate

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 19(Suppl 21),2,1992

Safety Information

Symbol	GHS02, GHS08
Signal Word	Danger
Hazard Statements	H228-H334-H351
Precautionary Statements	P210-P261-P281-P342 + P311
Personal Protective Equipment	Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes	F:Flammable;T:Toxic;
Risk Phrases	R45;R11
Safety Phrases	S36/37
RIDADR	UN 1325 4.1/PG 2
WGK Germany	3
RTECS	QR6135000
Packaging Group	I
Hazard Class	4.2

Articles5

Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines.

Dalton Trans. 43(42) , 15997-6005, (2014)

Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while main...

Nickel-catalyzed thioallylation of alkynes with allyl phenyl sulfides.

Org. Lett. 9 , 263, (2007)

Allylic sulfides add to alkynes in the presence of nickel complexes efficiently to afford thio-1,4-dienes regio- and stereoselectively. Functional groups such as alkoxy, siloxy, hydroxy, carboalkoxy, ...

A boron-doped helicene as a highly soluble, benchtop-stable green emitter.

Chem. Commun. (Camb.) 51(87) , 15808-10, (2015)

The high-yield synthesis of a boron-doped [4]helicene was achieved through a Ni-mediated Yamamoto C-C-coupling reaction; the moderate distortion of the molecular scaffold confers excellent solubility ...

Synonyms

EINECS 215-072-0

Bis(cyclooctadiene)nickel Ni(COD)2

1,2,5,6-Cyclooctanetetraylidene - nickel (2:1)

1,2,5,6-cyclooctanetetraylidene, nickel salt

(1Z,5Z)-cycloocta-1,5-diene,nickel

cyclooctane-1,2,5,6-tetraylidene - nickel (2:1)

1,2,5,6-Cyclooctanetetraylidene, nickel salt (2:1)

MFCD00058902

Recommended......