CAS 905709-79-7|[Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride
Introduction：Basic information about CAS 905709-79-7|[Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | [Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride | ||
|---|---|---|---|
| CAS Number | 905709-79-7 | Molecular Weight | 900.81200 |
| Density | / | Boiling Point | / |
| Molecular Formula | C49H46Cl2O2P2Ru | Melting Point | / |
| MSDS | ChineseUSA | Flash Point | / |
Names
| Name | [Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride |
|---|
Chemical & Physical Properties
| Molecular Formula | C49H46Cl2O2P2Ru |
|---|---|
| Molecular Weight | 900.81200 |
| Exact Mass | 900.13900 |
| PSA | 45.64000 |
| LogP | 4.15770 |
| InChIKey | BOERIKXMDOKSHH-UHFFFAOYSA-L |
| SMILES | Cc1ccc(C(C)C)cc1.Cl[Ru+].[Cl-].c1ccc(P(c2ccccc2)c2cccc3c2-c2c(cccc2P(c2ccccc2)c2ccccc2)OCCCO3)cc1 |
Safety Information
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| RIDADR | NONH for all modes of transport |
Articles3
More Articles| Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters. J. Org. Chem. 65 , 6223, (2000) | |
| Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates. J. Am. Chem. Soc. 125 , 9570, (2003) Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPh... | |
| Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols. J. Am. Chem. Soc. 126 , 1626, (2004) A new type of alpha-phthalimide ketones was hydrogenated in excellent enantioselectivity by using a Ru-(C3-TunePhos) complex as the catalyst. Up to 10 000 turnovers have been achieved in more than 99%... |
