Introduction：Basic information about CAS 15956-28-2|Dirhodium tetraacetate, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Dirhodium tetraacetate is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
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Chemical & Physical Properties
Boiling Point
117.1ºC at 760 mmHg
Melting Point
205ºC
Molecular Formula
C8H12O8Rh2
Molecular Weight
441.99
Flash Point
40ºC
Exact Mass
441.864227
PSA
105.20000
LogP
0.05520
Vapour Pressure
13.9mmHg at 25°C
InChIKey
DRGVLUZIGUIMLB-UHFFFAOYSA-N
SMILES
CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Rh].[Rh]
Storage condition
Store below +30°C.
Water Solubility
Soluble in aqueous solution like water. Slightly soluble in ethanol
Toxicological Information
CHEMICAL IDENTIFICATION
RTECS NUMBER :
VI9361000
CHEMICAL NAME :
Rhodium, tetrakis(mu-acetato)di-
CAS REGISTRY NUMBER :
15956-28-2
LAST UPDATED :
198909
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C8-H12-O8-Rh2
MOLECULAR WEIGHT :
442.02
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
TYPE OF TEST :
LD10 - Lethal Dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
115 mg/kg
TOXIC EFFECTS :
Tumorigenic - active as anti-cancer agent
REFERENCE :
JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 20,943,1977
Rhodium acetate/base-catalyzed N-silylation of indole derivatives with hydrosilanes.
Chem. Commun. (Camb.) 48(74) , 9269-71, (2012)
In the presence of Rh(2)(OAc)(4) (OAc = acetate) and TBA(2)WO(4) (TBA = tetra-n-butylammonium), the N-silylation of indole derivatives with hydrosilanes efficiently proceeded to give the corresponding...
One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay.
Org. Lett. 17(1) , 66-9, (2015)
4-N-allylarylpropylamino-1-sulfonyl triazoles are converted to structurally unique benzopyrrolizidinyl sulfonamides in a one-pot operation. Intramolecular capture of rhodium carbene with arylamino nit...
Unprecedented head-to-head conformers of d(GpG) bound to the antitumor active compound tetrakis (mu-carboxylato)dirhodium(II,II).
J. Am. Chem. Soc. 125(35) , 10703-13, (2003)
The N7/O6 equatorial binding interactions of the antitumor active complex Rh(2)(OAc)(4)(H(2)O)(2) (OAc(-) = CH(3)CO(2)(-)) with the DNA fragment d(GpG) have been unambiguously determined by NMR spectr...
