CAS 67719-69-1|tebbe reagent

Introduction:Basic information about CAS 67719-69-1|tebbe reagent, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Nametebbe reagent
CAS Number67719-69-1Molecular Weight284.58400
Density0.927Boiling Point/
Molecular FormulaC13H18AlClTiMelting Point/
MSDS/Flash Point4ºC
Symbol
GHS02, GHS05, GHS07, GHS08
Signal WordDanger

Names

Namemu-Chloro-mu-Methylene[Bis(Cyclopentadienyl)Titanium]Dimethylaluminum
SynonymMore Synonyms

Chemical & Physical Properties

Density0.927
Molecular FormulaC13H18AlClTi
Molecular Weight284.58400
Flash Point4ºC
Exact Mass284.03900
LogP4.36090
Appearance of CharactersSolution | Dark red to purple
Storage conditionRefrigerator
Water SolubilitySoluble in toluene, benzene, dichloromethane. Insoluble in water.

Safety Information

Symbol
GHS02, GHS05, GHS07, GHS08
Signal WordDanger
Hazard StatementsH225-H304-H314-H336-H361d-H373
Precautionary StatementsP210-P261-P280-P301 + P310-P305 + P351 + P338-P310
Personal Protective EquipmentFaceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard CodesF:Highlyflammable;T:Toxic;
Risk PhrasesR11;R23/24/25;R34
Safety PhrasesS16-S25-S29-S33-S36/37/39
RIDADRUN 2924 3/PG 2
WGK Germany2
Packaging GroupII
Hazard Class4.3
HS Code29310099

Articles3

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Synthesis and in vitro trypanocide activity of several polycyclic drimane-quinone derivatives.

Bioorg. Med. Chem. 11 , 2489-2497, (2003)

The Diels-Alder reaction between two polygodial-derived dienes and simple quinones to yield substituted naphtho- and anthraquinones, is described. The in vitro trypanocide activity for the series was ...

Synthesis of a novel ceramide analogue via Tebbe methylenation and evaluation of its antiproliferative activity.

Org. Lett. 7 , 1645, (2005)

[reaction: see text] A new analogue of (2S,3R)-ceramide (2) with a methylene group at C4 has been synthesized from d-tartaric acid (3) by using Tebbe methylenation as the key step. Compound 2 exhibite...

Synthesis , 165, (1991)

Synonyms

MFCD00151575
tebbe reagent
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