CAS 80-15-9|Cumyl hydroperoxide
Introduction：Basic information about CAS 80-15-9|Cumyl hydroperoxide, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | Cumyl hydroperoxide | ||
|---|---|---|---|
| CAS Number | 80-15-9 | Molecular Weight | 152.190 |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 225.1±0.0 °C at 760 mmHg |
| Molecular Formula | C9H12O2 | Melting Point | -30 °C |
| MSDS | ChineseUSA | Flash Point | 56.1±0.0 °C |
| Symbol | GHS02, GHS05, GHS06, GHS08, GHS09 | Signal Word | Danger |
Names
| Name | cumene hydroperoxide |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 1.1±0.1 g/cm3 |
|---|---|
| Boiling Point | 225.1±0.0 °C at 760 mmHg |
| Melting Point | -30 °C |
| Molecular Formula | C9H12O2 |
| Molecular Weight | 152.190 |
| Flash Point | 56.1±0.0 °C |
| Exact Mass | 152.083725 |
| PSA | 29.46000 |
| LogP | 2.63 |
| Vapour density | 5.4 (vs air) |
| Vapour Pressure | 0.1±0.4 mmHg at 25°C |
| Index of Refraction | 1.515 |
| InChIKey | YQHLDYVWEZKEOX-UHFFFAOYSA-N |
| SMILES | CC(C)(OO)c1ccccc1 |
| Stability | Stable. combustible. Strong oxidizer. Incompatible with a variety of organic materials, reacting vigorously or violently with acids, reducing agents, many metals, strong alkalies. Heat sensitive, decomposing explosively. |
| Water Solubility | Slightly soluble |
Toxicological Information
CHEMICAL IDENTIFICATION |
ACUTE TOXICITY DATA - TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 382 mg/kg
- TOXIC EFFECTS :
- Kidney, Ureter, Bladder - hematuria
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 220 ppm/4H
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - dyspnea
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 500 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold Kidney, Ureter, Bladder - hematuria
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 95 mg/kg
- TOXIC EFFECTS :
- Behavioral - muscle weakness Behavioral - ataxia
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 382 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 200 ppm/4H
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - dyspnea
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 270 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 490 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 1200 mg/kg
- TOXIC EFFECTS :
- Cardiac - pulse rate increase, without fall in BP Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - body temperature decrease
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1604 mg/kg/7W-I
- TOXIC EFFECTS :
- Related to Chronic Data - death
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 50 ppm/4H/3D-I
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - other changes Kidney, Ureter, Bladder - other changes Related to Chronic Data - death
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 399 mg/kg/7W-I
- TOXIC EFFECTS :
- Related to Chronic Data - death
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 8844 mg/kg/67W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 304 mg/kg
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - lymphoma, including Hodgkin's disease Skin and Appendages - tumors
MUTATION DATA - TYPE OF TEST :
- Gene conversion and mitotic recombination
- TEST SYSTEM :
- Yeast - Saccharomyces cerevisiae
- DOSE/DURATION :
- 47 mg/L
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 308,159,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1346 No. of Facilities: 4311 (estimated) No. of Industries: 80 No. of Occupations: 53 No. of Employees: 95676 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1346 No. of Facilities: 10989 (estimated) No. of Industries: 125 No. of Occupations: 85 No. of Employees: 234305 (estimated) No. of Female Employees: 69933 (estimated)
- TYPE OF TEST :
- Gene conversion and mitotic recombination
- TEST SYSTEM :
- Yeast - Saccharomyces cerevisiae
- DOSE/DURATION :
- 47 mg/L
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 308,159,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1346 No. of Facilities: 4311 (estimated) No. of Industries: 80 No. of Occupations: 53 No. of Employees: 95676 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1346 No. of Facilities: 10989 (estimated) No. of Industries: 125 No. of Occupations: 85 No. of Employees: 234305 (estimated) No. of Female Employees: 69933 (estimated)
Safety Information
| Symbol | GHS02, GHS05, GHS06, GHS08, GHS09 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H226-H242-H302 + H312-H304-H314-H331-H335-H373-H411 |
| Precautionary Statements | P210-P260-P280-P304 + P340 + P310-P305 + P351 + P338 + P310-P370 + P378 |
| Personal Protective Equipment | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | T:Toxic |
| Risk Phrases | R21/22;R23;R34;R48/20/22;R51/53;R7 |
| Safety Phrases | S14-S3/7-S36/37/39-S45-S50-S61-S14A-S26 |
| RIDADR | UN 3109 5.2 |
| WGK Germany | 3 |
| RTECS | MX2450000 |
| Packaging Group | II |
| Hazard Class | 5.2 |
| HS Code | 2909600000 |
Customs
| HS Code | 2909600000 |
|---|---|
| Summary | 2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |
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Synonyms
| 2-Phenyl-2-propyl hydroperoxide |
| Cumene hydroperoxide |
| 2-Phenylpropan-2-yl hydroperoxide |
| MFCD00002129 |
| 2-hydroperoxypropan-2-ylbenzene |
| Hyperiz |
| Trigonox R 239A |
| a,a-Dimethylbenzyl Hydroperoxide |
| a-Cumyl Hydroperoxide |
| 1-Methyl-1-phenylethylhydroperoxide |
| Kayacumene H |
| EINECS 201-254-7 |
| Percumyl H 80 |
| R 239A |
| Hydroperoxide, 1-methyl-1-phenylethyl |
| 2-Hydroperoxy-2-phenylpropane |
| Trigonox K 80 |
| Percumyl H |
| a,a-Dimethylbenzylhydroperoxide |
| a-Cumene Hydroperoxide |
| Trigonox R 239R |
| 1-Methyl-1-phenylethyl hydroperoxide |
| 2-Phenyl-2-propanyl hydroperoxide |
| Hydroperoxide, α,α-dimethylbenzyl |
