CAS 1142811-12-8|tBuXPhos Pd G1

Introduction:Basic information about CAS 1142811-12-8|tBuXPhos Pd G1, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NametBuXPhos Pd G1
CAS Number1142811-12-8Molecular Weight686.686
Density/Boiling Point/
Molecular FormulaC37H55ClNPPdMelting Point150-159℃
MSDSUSAFlash Point/
Symbol
GHS07, GHS08
Signal WordWarning

Names

Namechloropalladium(1+),ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane,2-phenylethanamine
SynonymMore Synonyms

Chemical & Physical Properties

Melting Point150-159℃
Molecular FormulaC37H55ClNPPd
Molecular Weight686.686
Exact Mass685.279541
PSA39.61000
LogP8.12030
InChIKeyGITFHTZGVMIBGS-UHFFFAOYSA-M
SMILESCC(C)c1cc(C(C)C)c(-c2ccccc2P(C(C)(C)C)C(C)(C)C)c(C(C)C)c1.Cl[Pd+].NCCc1[c-]cccc1

Safety Information

Symbol
GHS07, GHS08
Signal WordWarning
Hazard StatementsH315-H319-H335-H351
Precautionary StatementsP261-P281-P305 + P351 + P338
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Gloves
Hazard CodesXn
Risk Phrases36/37/38-40
Safety Phrases26-36/37
RIDADRNONH for all modes of transport

Articles4

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Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...

Synonyms

Chloropalladium(1+) (2-aminoethyl)benzenide - bis(2-methyl-2-propanyl)(2',4',6'-triisopropyl-2-biphenylyl)phosphine (1:1:1)
tBuXPhos Pd G1
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