CAS 99105-77-8|sulcotrione

Introduction:Basic information about CAS 99105-77-8|sulcotrione, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Namesulcotrione
CAS Number99105-77-8Molecular Weight328.768
Density1.4±0.1 g/cm3Boiling Point574.5±50.0 °C at 760 mmHg
Molecular FormulaC14H13ClO5SMelting Point139ºC
MSDSChineseUSAFlash Point301.2±30.1 °C
Symbol
GHS08, GHS09
Signal WordWarning

Names

Namesulcotrione
SynonymMore Synonyms

sulcotrione BiologicalActivity

DescriptionSulcotrione is a β-triketone herbicide which can inhibit hydroxyphenylpyruvate dioxygenase (HPPD).
Related CatalogSignaling Pathways >>Others >>OthersResearch Areas >>Others
Target

HPPD[1]

In VitroThe results show that sulcotrione behaves as time-independent reversible inhibitor. Similar results are previously described for natural β-triketones, and for the synthetic β-triketone NTBC. However it is the first time that such behavior is observed using a purified hydroxyphenylpyruvate dioxygenase (HPPD) and a synthetic β-triketone, namely sulcotrione. Inhibition kinetic analysis, performing with 3 hydroxyphenylpyruvate (HPP) and sulcotrione concentrations, show that the apparent KM increasing with sulcotrione concentration. This behavior is consistent with the data present in the literature, describing sulcotrione as a competitive inhibitor of HPPD[1].
Kinase AssayElectrochemical behavior of sulcotrione at 0.2 mg/L is characterized by cyclic voltammetry. Preliminary HPPD inhibition assays are performed by incubating the enzyme during time periods ranging from 2 to 10 min in presence of sulcotrione at differnt concentrations[1].
References

[1]. Rocaboy-Faquet E, et al. A novel amperometric biosensor for ß-triketone herbicides based on hydroxyphenylpyruvatedioxygenase inhibition: A case study for sulcotrione. Talanta. 2016;146:510-6.

Chemical & Physical Properties

Density1.4±0.1 g/cm3
Boiling Point574.5±50.0 °C at 760 mmHg
Melting Point139ºC
Molecular FormulaC14H13ClO5S
Molecular Weight328.768
Flash Point301.2±30.1 °C
Exact Mass328.017212
PSA93.73000
LogP0.21
Vapour Pressure0.0±1.6 mmHg at 25°C
Index of Refraction1.572
InChIKeyPQTBTIFWAXVEPB-UHFFFAOYSA-N
SMILESCS(=O)(=O)c1ccc(C(=O)C2C(=O)CCCC2=O)c(Cl)c1

Safety Information

Symbol
GHS08, GHS09
Signal WordWarning
Hazard StatementsH361-H373-H410
Precautionary StatementsP273-P281-P501
Target OrgansKidney
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard CodesXi:Irritant;
Risk PhrasesR43
Safety PhrasesS36/37
RIDADRUN 3077 9 / PGIII
HS Code2930909056

Customs

HS Code2930909056
Summary2930909056 2,6-dichlorobenzothioamide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

Articles28

More Articles
Novel bioassay for the discovery of inhibitors of the 2-C-methyl-D-erythritol 4-phosphate (MEP) and terpenoid pathways leading to carotenoid biosynthesis.

PLoS ONE 9(7) , e103704, (2014)

The 2-C-methyl-D-erythritol 4-phosphate (MEP) pathway leads to the synthesis of isopentenyl diphosphate in plastids. It is a major branch point providing precursors for the synthesis of carotenoids, t...

Glyphosate adsorption in soils compared to herbicides replaced with the introduction of glyphosate resistant crops.

Chemosphere 61(6) , 844-55, (2005)

Use of glyphosate resistant crops was helpful in addressing observed increases in environmental contamination by herbicides. Glyphosate is a broad-spectrum herbicide, and its behaviour-as well as that...

Isolation and characterization of Bradyrhizobium sp. SR1 degrading two β-triketone herbicides.

Environ. Sci. Pollut. Res. Int. 23 , 4138-48, (2016)

In this study, a bacterial strain able to use sulcotrione, a β-triketone herbicide, as sole source of carbon and energy was isolated from soil samples previously treated with this herbicide. Phylogene...

Synonyms

1,3-Cyclohexanedione, 2-[2-chloro-4-(methylsulfonyl)benzoyl]-
Mikado
SC0051
chlormesulone
2-[2-Chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione
sulcotrione
2-[2-chloro-4-(methanesulfonyl)benzoyl]cyclohexane-1,3-dione
L6V CVTJ BVR BG DSW1
GALLEON
CHLORMESULON
2-(2-chloro-4-methylsulfonylbenzoyl)-cyclohexane-1,3-dione
2-(2-chloro-4-methylsulphonylbenzoyl)cyclohexane-1,3-dione
2-(2-chloro-4-(methylsulfonyl)benzoyl)-1,3-cyclohexanwdione
2-(2-Chlor-4-(methylsulfonyl)-benzoyl)-1,3-cyclohexandion
2-(2-chloro-4-mesylbenzoyl)-cyclohexane-1,3-dione
2-(2-Chloro-4-methanesulfonylbenzoyl)-cyclohexane-1,3-dione
ICIA0051
2-(2-Chloro-4-mesylbenzoyl)cyclohexane-1,3-dione
2-[2-chloro-4-(methylsulfonyl)-benzoyl]-1,3-cyclohexanedione
SULCOTRIONE,MESOTRIONE
CAS 13054-03-0|H-Gly-Pro-Gly-Gly-OH
CAS 25606-41-1|PROPAMOCARB HYDROCHLORIDE
Recommended......
TOP