CAS 301224-40-8|Hoveyda-Grubbs II

Introduction：Basic information about CAS 301224-40-8|Hoveyda-Grubbs II, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Safety Information
4. Customs
5. Articles11
6. Synonyms

Common Name	Hoveyda-Grubbs II
CAS Number	301224-40-8	Molecular Weight	626.622
Density	/	Boiling Point	/
Molecular Formula	C₃₁H₃₈Cl₂N₂ORu	Melting Point	216-220ºC(lit.)
MSDS	USA	Flash Point	/

Names

Name	[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-propan-2-yloxyphenyl)methylidene]ruthenium
Synonym	More Synonyms

Chemical & Physical Properties

Melting Point	216-220ºC(lit.)
Molecular Formula	C₃₁H₃₈Cl₂N₂ORu
Molecular Weight	626.622
Exact Mass	626.140503
PSA	15.71000
LogP	8.18270
InChIKey	ZRPFJAPZDXQHSM-UHFFFAOYSA-L
SMILES	Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)C2=[Ru](Cl)(Cl)=Cc2ccccc2OC(C)C)c(C)c1
Storage condition	2~8 ℃

Safety Information

Personal Protective Equipment	Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes	Xi
RIDADR	NONH for all modes of transport
HS Code	2933990090

Customs

HS Code	2933990090
Summary	2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles11

Highly efficient ruthenium catalysts for the formation of tetrasubstituted olefins via ring-closing metathesis.

Org. Lett. 9 , 1589, (2007)

[reaction: see text] A series of ruthenium-based metathesis catalysts with N-heterocyclic carbene (NHC) ligands have been prepared in which the N-aryl groups have been changed from mesityl to mono-ort...

Sequential catalysis: a metathesis/dihydroxylation sequence.

Angew. Chem. Int. Ed. Engl. 45 , 1900, (2006)

Ruthenium catalysed cross metathesis with fluorinated olefins.

Chem. Commun. (Camb.) , 1692, (2001)

The E-selective cross metathesis (CM) of fluorinated olefins with various functionalised alkenes in good to excellent yields is reported.

Synonyms

Dichloro(1,3-dimesityl-2-imidazolidinylidene)(2-isopropoxybenzylidene)ruthenium

Hoveyda-Grubbs II

Grubbs-Hoveyda second generationpre-catalyst

(1,3-Dimesityl-2-imidazolidinylidene)(2-isopropoxybenzylidene)ruthenium(2+) dichloride

Ruthenium(2+), [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[2-(1-methylethoxy)phenyl]methylene]-, chloride (1:2)

Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)phenyl]methylene]-

Hoveyda-Grubbs catalyst second-generation catalyst

Hoveyda-Grubbs Catalyst 2nd Generation

MFCD03701614

HOVEYDA-GRUBBS 2ND GENERATION

IHMes-o-isopropoxybenzylidene-ruthenium dichloride

(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium

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