CAS 203714-71-0|DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
Introduction：Basic information about CAS 203714-71-0|DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II), including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II) | ||
|---|---|---|---|
| CAS Number | 203714-71-0 | Molecular Weight | 600.606 |
| Density | / | Boiling Point | 383.4ºC at 760 mmHg |
| Molecular Formula | C28H45Cl2OPRu | Melting Point | 195-197ºC(lit.) |
| MSDS | ChineseUSA | Flash Point | 195.6ºC |
| Symbol | GHS02 | Signal Word | Warning |
Names
| Name | dichloro-[(2-propan-2-yloxyphenyl)methylidene]ruthenium,tricyclohexylphosphane |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Boiling Point | 383.4ºC at 760 mmHg |
|---|---|
| Melting Point | 195-197ºC(lit.) |
| Molecular Formula | C28H45Cl2OPRu |
| Molecular Weight | 600.606 |
| Flash Point | 195.6ºC |
| Exact Mass | 600.162903 |
| PSA | 22.82000 |
| LogP | 10.01880 |
| Vapour Pressure | 9.7E-06mmHg at 25°C |
| InChIKey | KMKCJXPECJFQPQ-UHFFFAOYSA-L |
| SMILES | C1CCC(P(C2CCCCC2)C2CCCCC2)CC1.CC(C)Oc1ccccc1C=[Ru](Cl)Cl |
| Storage condition | 2~8°C |
Safety Information
| Symbol | GHS02 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H228 |
| Precautionary Statements | P210 |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
| Hazard Codes | F+ |
| RIDADR | UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all |
Articles11
More Articles| Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts. Chem. Rev. 110 , 1746, (2010) | |
| Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article. Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000) The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decad... | |
| The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success story. Acc. Chem. Res. 34 , 18, (2001) In recent years, the olefin metathesis reaction has attracted widespread attention as a versatile carbon-carbon bond-forming method. Many new applications have become possible because of major advance... |
Synonyms
| Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II) |
| Dichloro(2-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium (II) |
| Hoveyda-Grubbs Catalyst 1st Generation |
| Hoveyda-Grubbs first generation catalyst |
| Phosphine, tricyclohexyl-, compd. with dichloro[[2-(1-methylethoxy)phenyl]methylene]ruthenium (1:1) |
| Dichloro(2-isopropoxybenzylidene)ruthenium - tricyclohexylphosphine (1:1) |
| MFCD03453042 |
| dichloro(tricyclohexylphosphine)-(o-isopropoxy-phenylmethylene)ruthenium(II) |
