CAS 836-30-6|4-Nitrodiphenylamine

Introduction：Basic information about CAS 836-30-6|4-Nitrodiphenylamine, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Toxicological Information
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
4. Safety Information
5. Customs
6. Articles3
7. Synonyms

Common Name	4-Nitrodiphenylamine
CAS Number	836-30-6	Molecular Weight	214.220
Density	1.3±0.1 g/cm3	Boiling Point	382.6±25.0 °C at 760 mmHg
Molecular Formula	C₁₂H₁₀N₂O₂	Melting Point	132-135 °C(lit.)
MSDS	ChineseUSA	Flash Point	185.2±23.2 °C
Symbol	GHS07	Signal Word	Warning

Names

Name	4-Nitrodiphenylamine
Synonym	More Synonyms

Chemical & Physical Properties

Density	1.3±0.1 g/cm3
Boiling Point	382.6±25.0 °C at 760 mmHg
Melting Point	132-135 °C(lit.)
Molecular Formula	C₁₂H₁₀N₂O₂
Molecular Weight	214.220
Flash Point	185.2±23.2 °C
Exact Mass	214.074234
PSA	57.85000
LogP	3.74
Vapour Pressure	0.0±0.9 mmHg at 25°C
Index of Refraction	1.666
InChIKey	XXYMSQQCBUKFHE-UHFFFAOYSA-N
SMILES	O=[N+]([O-])c1ccc(Nc2ccccc2)cc1
Water Solubility	INSOLUBLE

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: JJ9600000

CHEMICAL NAME :: Diphenylamine, 4-nitro-

CAS REGISTRY NUMBER :: 836-30-6

BEILSTEIN REFERENCE NO. :: 2051910

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C12-H10-N2-O2

MOLECULAR WEIGHT :: 214.24

WISWESSER LINE NOTATION :: WNR DMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >7940 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4 gm/kg

TOXIC EFFECTS :: Behavioral - excitement Behavioral - muscle contraction or spasticity Blood - hemorrhage

REFERENCE :: TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 8,126,1966

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >7940 mg/kg

TOXIC EFFECTS :: Behavioral - food intake (animal) Behavioral - changes in motor activity (specific assay)

REFERENCE :: ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,66,1990 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4095 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 348 (estimated) No. of Female Employees: 34 (estimated)

Safety Information

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes	Xi:Irritant;
Risk Phrases	R36/37/38
Safety Phrases	S26-S37/39
RIDADR	3077
WGK Germany	3
RTECS	JJ9600000
Packaging Group	III
Hazard Class	9
HS Code	2921440000

Customs

HS Code	2921440000
Summary	2921440000. diphenylamine and its derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles3

A novel method for the identification of inorganic and organic gunshot residue particles of lead-free ammunitions from the hands of shooters using scanning laser ablation-ICPMS and Raman micro-spectroscopy.

Analyst 139(23) , 6232-41, (2014)

A method based on scanning laser ablation and inductively coupled plasma-mass spectrometry (SLA-ICPMS) and Raman micro-spectroscopy for the detection and identification of compounds consistent with gu...

Reduction of Nitrated Diphenylamine Derivatives under Anaerobic Conditions.

Appl. Environ. Microbiol. 61(9) , 3282-7, (1995)

2-Nitrodiphenylamine, 4-nitrodiphenylamine, and 2,4-dinitrodiphenylamine were anaerobically metabolized in sediment-water batch enrichments inoculated with mud from the German North Sea coast. The fir...

Heterogeneous catalytic transfer hydrogenation of 4-nitrodiphenylamine to p-phenylenediamines. Banerjee AA and Mukesh D.

J. Chem. Soc. Chem. Commun. 18 , 1275-1276, (1988)

Synonyms

p-Nitrodiphenylamine

4-Nitro-N-phenylaniline

N-(4-Nitrophenyl)-N-phenylamine

EINECS 212-646-2

Benzenamine, 4-nitro-N-phenyl-

4-Nitrodiphenylamine

MFCD00007301

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