CAS 905459-27-0|dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladi

Introduction:Basic information about CAS 905459-27-0|dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladi, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Namedichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii)
CAS Number905459-27-0Molecular Weight681.475
Density/Boiling Point/
Molecular FormulaC32H42Cl3N3PdMelting Point240℃ (DEC.)
MSDSChineseUSAFlash Point/
Symbol
GHS07
Signal WordWarning

Names

Name[1,3-Bis(2,6-Diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride
SynonymMore Synonyms

Chemical & Physical Properties

Melting Point240℃ (DEC.)
Molecular FormulaC32H42Cl3N3Pd
Molecular Weight681.475
Exact Mass679.147888
PSA19.37000
LogP3.80850

Safety Information

Symbol
GHS07
Signal WordWarning
Hazard StatementsH302-H312-H332
Precautionary StatementsP280
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Gloves
Hazard CodesXn
Risk Phrases20/21/22
RIDADRNONH for all modes of transport
HS Code28439000

Articles6

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A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst.

Chemistry 12 , 4749, (2006)

We have developed the first user-friendly Negishi protocol capable of routinely cross-coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, ...

Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective.

Angew. Chem. Int. Ed. Engl. 46 , 2768, (2007)

Palladium-catalyzed C-C and C-N bond-forming reactions are among the most versatile and powerful synthetic methods. For the last 15 years, N-heterocyclic carbenes (NHCs) have enjoyed increasing popula...

Pd-catalyzed aryl amination mediated by well defined, N-heterocyclic carbene (NHC)-Pd precatalysts, PEPPSI.

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Pd-N-heterocyclic carbene (NHC)-catalyzed Buchwald-Hartwig amination protocols mediated by Pd-PEPPSI precatalysts is described. These protocols provide access to a range of hindered and functionalized...

Synonyms

1,3-bis[2,6-di(propan-2-yl)phenyl]-2H-imidazole,3-chloropyridine,dichloropalladium
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