CAS 5470-66-6|4-Nitro-2-picoline-N-oxide

Introduction：Basic information about CAS 5470-66-6|4-Nitro-2-picoline-N-oxide, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Toxicological Information
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
MUTATION DATA
4. Safety Information
5. Customs
6. Articles3
7. Synonyms

Common Name	4-Nitro-2-picoline-N-oxide
CAS Number	5470-66-6	Molecular Weight	154.123
Density	1.4±0.1 g/cm3	Boiling Point	404.0±25.0 °C at 760 mmHg
Molecular Formula	C₆H₆N₂O₃	Melting Point	155-159 °C(lit.)
MSDS	ChineseUSA	Flash Point	198.1±23.2 °C
Symbol	GHS07, GHS08	Signal Word	Warning

Names

Name	4-Nitro-2-picoline N-oxide
Synonym	More Synonyms

Chemical & Physical Properties

Density	1.4±0.1 g/cm3
Boiling Point	404.0±25.0 °C at 760 mmHg
Melting Point	155-159 °C(lit.)
Molecular Formula	C₆H₆N₂O₃
Molecular Weight	154.123
Flash Point	198.1±23.2 °C
Exact Mass	154.037842
PSA	71.28000
LogP	-0.09
Vapour Pressure	0.0±0.9 mmHg at 25°C
Index of Refraction	1.585
InChIKey	FTTIAVRPJGCXAC-UHFFFAOYSA-N
SMILES	Cc1cc([N+](=O)[O-])cc[n+]1[O-]
Storage condition	2-8°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UT5710000

CHEMICAL NAME :: Pyridine, 2-methyl-4-nitro-, 1-oxide

CAS REGISTRY NUMBER :: 5470-66-6

BEILSTEIN REFERENCE NO. :: 0135501

LAST UPDATED :: 199612

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C6-H6-N2-O3

MOLECULAR WEIGHT :: 154.14

WISWESSER LINE NOTATION :: T6NJ AO B1 DNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1800 mg/kg/15W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application

MUTATION DATA

TYPE OF TEST :: DNA damage

TEST SYSTEM :: Rodent - mouse Fibroblast

DOSE/DURATION :: 50 umol/L

REFERENCE :: CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 35,521,1975

Safety Information

Symbol	GHS07, GHS08
Signal Word	Warning
Hazard Statements	H302-H312-H315-H319-H332-H335-H351
Precautionary Statements	P261-P280-P305 + P351 + P338
Personal Protective Equipment	Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes	Xn:Harmful;
Risk Phrases	R20/21/22;R36/37/38;R40
Safety Phrases	S22-S26-S36
RIDADR	2811
WGK Germany	3
RTECS	UT5710000
Packaging Group	III
Hazard Class	6.1
HS Code	2933399090

Customs

HS Code	2933399090
Summary	2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles3

Redetermination of 2-methyl-4-nitro-pyridine N-oxide.

Acta Crystallogr. Sect. E Struct. Rep. Online 70(Pt 4) , o426-7, (2014)

An improved crystal structure of the title compound, C6H6N2O3, is reported. The structure, previously solved [Li et al. (1987 ▶). Jiegou Huaxue (Chin. J. Struct. Chem.), 6, 20-24] in the ortho-rhom-bi...

Mononuclear copper(II) nitrato complexes with methyl-substituted 4-nitropyridine N-oxide. Physicochemical and cytotoxic characteristics.

J. Inorg. Biochem. 104(2) , 153-60, (2010)

Three new complexes, products of the interaction of Cu(NO(3))(2) and methyl-substituted 4-nitropyridine N-oxides were synthesized and characterized by elemental analysis, magnetic, spectroscopic (IR, ...

Amination of alkyl substituted halogenopyridines with potassium amide in liquid ammonia. Van der Does L and Den Hertog HJ.

Rec. Trav. Chim. 91(12) , 1403-1413, (1972)

Synonyms

2-methyl-4-nitro-pyridine-N-oxide

2-methyl-4-nitro-1-oxidopyridin-1-ium

MFCD00014625

4-Nitro-2-methylpyridine-N-oxide

4-Nitro-2-picoline-N-oxide

Pyridine, 2-methyl-4-nitro-, 1-oxide

2-Methyl-4-nitropyridine 1-oxide

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