CAS 1191-15-7|Diisobutylaluminium hydride

Introduction：Basic information about CAS 1191-15-7|Diisobutylaluminium hydride, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Toxicological Information
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
4. Safety Information
5. Articles19
6. Synonyms

Common Name	Diisobutylaluminium hydride
CAS Number	1191-15-7	Molecular Weight	142.218
Density	1.23 g/mL at 25 °C	Boiling Point	65 °C
Molecular Formula	C₈H₁₉Al	Melting Point	-70 °C
MSDS	Chinese	Flash Point	40 °F
Symbol	GHS02, GHS05, GHS07, GHS08	Signal Word	Danger

Names

Name	Diisobutylaluminium hydride
Synonym	More Synonyms

Chemical & Physical Properties

Density	1.23 g/mL at 25 °C
Boiling Point	65 °C
Melting Point	-70 °C
Molecular Formula	C₈H₁₉Al
Molecular Weight	142.218
Flash Point	40 °F
Exact Mass	142.130219
LogP	3.33250
Storage condition	2-8°C
Water Solubility	vigorous reaction

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BD0710000

CHEMICAL NAME :: Aluminum, diisobutylhydro-

CAS REGISTRY NUMBER :: 1191-15-7

BEILSTEIN REFERENCE NO. :: 4123663

LAST UPDATED :: 199712

DATA ITEMS CITED :: 14

MOLECULAR FORMULA :: C8-H19-Al

MOLECULAR WEIGHT :: 142.25

WISWESSER LINE NOTATION :: 1Y1&1-AL-H1Y1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 70 gm/m3/1H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes

REFERENCE :: MELAAD Medicina del Lavoro. Industrial Medicine. (Via S. Barnaba, 8, 20122 Milan, Italy) V.16- 1925- Volume(issue)/page/year: 57,188,1966 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Safety Information

Symbol	GHS02, GHS05, GHS07, GHS08
Signal Word	Danger
Hazard Statements	H225-H250-H260-H304-H314-H336-H361d-H373
Precautionary Statements	P210-P222-P223-P231 + P232-P370 + P378-P422
Personal Protective Equipment	Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	F:Flammable;C:Corrosive;
Risk Phrases	R11;R14/15;R35;R48/20;R63;R65;R67
Safety Phrases	S26-S43-S45-S62-S46-S36/37/39-S29-S16-S61-S27
RIDADR	UN 3399 4.3/PG 1
WGK Germany	2
RTECS	BD0710000
Packaging Group	I
Hazard Class	4.3

Articles19

Use of multivariate statistical techniques to optimize the separation of 17 capsinoids by ultra performance liquid chromatography using different columns.

Talanta 134 , 256-63, (2015)

In this work a multivariate statistical tool (Derringer and Suich optimization) was proposed for the separation of seventeen capsinoids (natural and synthetic) using the UHPLC-DAD chromatography. Caps...

[Development of domino reactions based on skeletal rearrangement].

Yakugaku Zasshi 131(11) , 1563-73, (2011)

Domino reactions, which enable formations of several chemical bonds and multi-step transformation in one-pot process, have received much attention as an efficient synthetic methodology to preserve che...

DIBAL-mediated reductive transformation of trans-dimethyl tartrate acetonide into ε-hydroxy α,β-unsaturated ester and its derivatives.

J. Org. Chem. 76(11) , 4669-74, (2011)

Stepwise, selective DIBAL reduction of the acetonide diester derived from tartaric acid followed by the Horner-Emmons reaction effectively provided desymmetrized hydroxy mono-olefination products in a...

Synonyms

Hydrido(diisobutyl)aluminium

EINECS 214-729-9

DIBAH

Diisobutylaluminum hydride

Aluminum, hydrobis(2-methylpropyl)-

DIBAL

Di-iso-butylaluminum hydride

Hydrodiisobutylaluminum

MFCD00008928

bis(2-methylpropyl)aluminum

Diisobutylaluminium hydride

hidruro de diisobutilaluminio

Diisobutylhydroaluminum

DIBAL-H DIBAL

DIBAL-H

Diisobutylaluminumhydride

di-isobutylaluminium hydride

Hydrido(diisobutyl)aluminum

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