CAS 20069-09-4|Piplartine

Introduction:Basic information about CAS 20069-09-4|Piplartine, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NamePiplartine
CAS Number20069-09-4Molecular Weight317.336
Density1.2±0.1 g/cm3Boiling Point475.6±45.0 °C at 760 mmHg
Molecular FormulaC17H19NO5Melting Point124ºC
MSDSChineseUSAFlash Point241.4±28.7 °C

Names

NamePiperlongumine
SynonymMore Synonyms

Piplartine BiologicalActivity

DescriptionPiperlongumine is a natural alkaloid isolated from Piper longum Linn[1], possesses ant-inflammatory, antibacterial, antiangiogenic, antioxidant, antitumor, and antidiabetic activities[2]. Piperlongumine induces ROS, and induces apoptosis in cancer cell lines[1]. Piperlongumine shows anti-cardiac fibrosis activity, suppresses myofibroblast transformation via suppression of the ERK1/2 signaling pathway[2].
Related CatalogSignaling Pathways >>MAPK/ERK Pathway >>ERKSignaling Pathways >>Stem Cell/Wnt >>ERKNatural Products >>AlkaloidResearch Areas >>CancerResearch Areas >>Cardiovascular DiseaseResearch Areas >>Infection
Target

ERK1

ERK2

In VitroPiplartine (5, 10, and 15 μM) significantly decreases cell proliferation of 786-O, SKBR3, Panc1, A549, and L3.6pL cancer cells after treatment for 24 and 48 hours, induces apoptosis and ROS in these cell lines at 5 and 10 μM after 3 or 9 h of treatment[1]. Piplartine (5 or 10 μM) induces cleaved PARP and downregulates Sp1, Sp3, Sp4, and Sp-regulated genes[1]. Piplartine (20 μM) decreases the viability of cardiac fibroblasts (CFs). Piplartine (0-10 μM) suppresses myofibroblast transformation via suppression of the ERK1/2 signaling pathway[2].
In VivoPiperlongumine (30 mg/kg/day, i.p. for 3 weeks) exhibits potent anti-tumor effect in athymic nude mice bearing L3.6pL cells without body weight loss[1].
References

[1]. Karki K, et al. Piperlongumine Induces Reactive Oxygen Species (ROS)-Dependent Downregulation of Specificity Protein Transcription Factors.

[2]. Wu X, e,t al. Piperlongumine inhibits angiotensin II-induced extracellular matrix expression in cardiac fibroblasts. J Cell Biochem. 2018 Dec;119(12):10358-10364

Chemical & Physical Properties

Density1.2±0.1 g/cm3
Boiling Point475.6±45.0 °C at 760 mmHg
Melting Point124ºC
Molecular FormulaC17H19NO5
Molecular Weight317.336
Flash Point241.4±28.7 °C
Exact Mass317.126312
PSA65.07000
LogP2.34
Appearance of Characterswhite to beige
Vapour Pressure0.0±1.2 mmHg at 25°C
Index of Refraction1.581
InChIKeyVABYUUZNAVQNPG-BQYQJAHWSA-N
SMILESCOc1cc(C=CC(=O)N2CCC=CC2=O)cc(OC)c1OC
Storage condition2-8°C
Water SolubilityDMSO: ≥5mg/mL at warmed to 60°C

Safety Information

RIDADRNONH for all modes of transport
WGK Germany3
RTECSUU7785850
HS Code2933399090

Customs

HS Code2933399090
Summary2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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Synonyms

Piperlongumine
1-[(E)-3-(3,4,5-trimethoxyphenyl)prop-2-enoyl]-2,3-dihydropyridin-6-one
2(1H)-Pyridinone, 5,6-dihydro-1-[(2E)-1-oxo-3-(3,4,5-trimethoxyphenyl)-2-propen-1-yl]-
(E)-Piplartine
1-[(2E)-3-(3,4,5-Trimethoxyphenyl)-2-propenoyl]-5,6-dihydro-2(1H)-pyridinone
piplartine
1-[3-(3,4,5-Trimethoxy-phenyl)-acryloyl]-5,6-dihydro-1H-pyridin-2-one
2(1H)-Pyridinone, 5,6-dihydro-1-(1-oxo-3-(3,4,5-trimethoxyphenyl)-2-propenyl)-, (E)-
1-[(2E)-3-(3,4,5-Trimethoxyphenyl)prop-2-enoyl]-5,6-dihydropyridin-2(1H)-one
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