CAS 123-62-6|Propionic anhydride

Introduction:Basic information about CAS 123-62-6|Propionic anhydride, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NamePropionic anhydride
CAS Number123-62-6Molecular Weight130.142
Density1.0±0.1 g/cm3Boiling Point168.4±8.0 °C at 760 mmHg
Molecular FormulaC6H10O3Melting Point-42 °C
MSDSChineseUSAFlash Point73.9±0.0 °C
Symbol
GHS05
Signal WordDanger

Names

NamePropionic anhydride
SynonymMore Synonyms

Chemical & Physical Properties

Density1.0±0.1 g/cm3
Boiling Point168.4±8.0 °C at 760 mmHg
Melting Point-42 °C
Molecular FormulaC6H10O3
Molecular Weight130.142
Flash Point73.9±0.0 °C
Exact Mass130.062988
PSA43.37000
LogP0.58
Vapour density4.5 (vs air)
Vapour Pressure1.6±0.3 mmHg at 25°C
Index of Refraction1.408
InChIKeyWYVAMUWZEOHJOQ-UHFFFAOYSA-N
SMILESCCC(=O)OC(=O)CC
StabilityStable. Combustible. Incompatible with strong oxidizing agents, water, moisture, most common metals, active halogen compounds, ammonia, amines.
Water Solubilityhydrolyses

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UF9100000
CHEMICAL NAME :
Propionic anhydride
CAS REGISTRY NUMBER :
123-62-6
BEILSTEIN REFERENCE NO. :
0507066
LAST UPDATED :
199806
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C6-H10-O3
MOLECULAR WEIGHT :
130.16
WISWESSER LINE NOTATION :
2VOV2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 12/15/1970 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2360 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
10 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
1 mL/kg
TOXIC EFFECTS :
Skin and Appendages - dermatitis, other (after systemic exposure)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0533570 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1181 No. of Facilities: 33 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 66 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1181 No. of Facilities: 3 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 489 (estimated) No. of Female Employees: 32 (estimated)

Safety Information

Symbol
GHS05
Signal WordDanger
Hazard StatementsH314
Precautionary StatementsP280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
Personal Protective EquipmentFaceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard CodesC:Corrosive;
Risk PhrasesR34
Safety PhrasesS26-S45
RIDADRUN 2496 8/PG 3
WGK Germany1
RTECSUF9100000
Packaging GroupIII
Hazard Class8
HS Code2942000000

Customs

HS Code2915900090
Summary2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

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Synonyms

propionic acid anhydride
Propanoic anhydride
Propanoic acid, anhydride
EINECS 204-638-2
Propionic anhydride
propanoyl propanoate
MFCD00009303
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