CAS 14264-16-5|Bis(triphenylphosphine)nickel(II)chloride

Introduction:Basic information about CAS 14264-16-5|Bis(triphenylphosphine)nickel(II)chloride, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NameBis(triphenylphosphine)nickel(II)chloride
CAS Number14264-16-5Molecular Weight654.17000
Density/Boiling Point360ºCat 760 mmHg
Molecular FormulaC36H30Cl2NiP2Melting Point250ºC (dec.)
MSDSChineseUSAFlash Point181.7ºC
Symbol
GHS07, GHS08
Signal WordDanger

Names

NameBis(triphenylphosphine)nickel(II) Dichloride
SynonymMore Synonyms

Chemical & Physical Properties

Boiling Point360ºCat 760 mmHg
Melting Point250ºC (dec.)
Molecular FormulaC36H30Cl2NiP2
Molecular Weight654.17000
Flash Point181.7ºC
Exact Mass652.05500
PSA27.18000
LogP4.58310
InChIKeyZBRJXVVKPBZPAN-UHFFFAOYSA-L
SMILESCl[Ni]Cl.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
Water Solubilityinsoluble

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QR6170000
CHEMICAL NAME :
Nickel, bis(triphenylphosphine)dichloro-
CAS REGISTRY NUMBER :
14264-16-5
LAST UPDATED :
199701
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C36-H30-Cl2-Ni-P2
MOLECULAR WEIGHT :
654.21
WISWESSER LINE NOTATION :
4P4&4 2 &G-NI-G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03119 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

Symbol
GHS07, GHS08
Signal WordDanger
Hazard StatementsH317-H350
Precautionary StatementsP201-P280-P308 + P313
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
Hazard CodesT:Toxic;
Risk PhrasesR20/21/22;R34;R45
Safety PhrasesS26-S36/37/39-S45-S53
RIDADRUN2923
WGK Germany3
RTECSQR6170000
Packaging GroupIII
Hazard Class6.1(b)
HS Code29310095

Customs

HS Code29310095

Synonyms

EINECS 238-154-8
Bis(triphenylphosphine)nickel(II) dichloride
MFCD00009592
Bis(triphenylphosphine)nickel(II)chloride
NiCl2(PPh3)2
Dichlorobis(triphenylphosphine)nickel(II)
Nickel(II)bis(triphenylphosphine) dichloride
Phosphine, tributyl-, compd. with nickelchloride (2_1)
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