CAS 14024-58-9|2,4-Pentanedione-manganese (2:1)

Introduction:Basic information about CAS 14024-58-9|2,4-Pentanedione-manganese (2:1), including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Name2,4-Pentanedione-manganese (2:1)
CAS Number14024-58-9Molecular Weight255.170
Density1.6 g/cm3Boiling Point138.4ºC at 760 mmHg
Molecular FormulaC10H16MnO4Melting Point180ºC
MSDSChineseUSAFlash Point43.1ºC
Symbol
GHS07, GHS08
Signal WordWarning

Names

NameBis(2,4-pentanedionato)manganese(II) Dihydrate
SynonymMore Synonyms

Chemical & Physical Properties

Density1.6 g/cm3
Boiling Point138.4ºC at 760 mmHg
Melting Point180ºC
Molecular FormulaC10H16MnO4
Molecular Weight255.170
Flash Point43.1ºC
Exact Mass255.042908
PSA68.28000
LogP1.10900
Vapour Pressure0.174mmHg at 25°C
InChIKeyVNNDVNZCGCCIPA-UHFFFAOYSA-N
SMILESCC(=O)C=C(C)O.CC(=O)C=C(C)O.[Mn]
Stabilityhygroscopic
Water Solubility11.5g/l | Soluble in water

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OO9350000
CHEMICAL NAME :
Manganese, bis(2,4-pentanedionato-O,O')-
CAS REGISTRY NUMBER :
14024-58-9
LAST UPDATED :
199701
DATA ITEMS CITED :
21
MOLECULAR FORMULA :
C10-H14-Mn-O4
MOLECULAR WEIGHT :
253.18

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1200 mg/kg/26W-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Tumorigenic - tumors at site of application
REFERENCE :
JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 60,1171,1978
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1350 mg/kg/21W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Musculoskeletal - tumors Tumorigenic - tumors at site of application
REFERENCE :
NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. (San Francisco, CA 94117) Volume(issue)/page/year: PH43-64-886 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Safety Information

Symbol
GHS07, GHS08
Signal WordWarning
Hazard StatementsH302 + H312 + H332-H315-H319-H335-H351
Precautionary StatementsP261-P280-P305 + P351 + P338
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Gloves
Hazard CodesXn: Harmful;
Risk PhrasesR20/21/22
Safety PhrasesS26;S36
RIDADRNONH for all modes of transport
WGK Germany3
RTECSOO9350000

Articles32

More Articles
Maleimidyl magnetic nanoplatform for facile molecular MRI.

Nanotechnology 25(27) , 275102, (2014)

In this study, we developed the maleimidyl magnetic nanoplatform, which enables functional targeting of a biomarker-specific moiety for molecular imaging via MRI. The maleimide group of the maleimidyl...

Local vanadium release from a calcium sulfate carrier accelerates fracture healing.

J. Orthop. Res. 32(5) , 727-34, (2014)

This study evaluated the efficacy of using calcium sulfate (CaSO4 ) as a carrier for intramedullary delivery of an organic vanadium salt, vanadyl acetylacetonate (VAC) after femoral fracture. VAC can ...

Size- and shape-dependent peroxidase-like catalytic activity of MnFe2O4 Nanoparticles and their applications in highly efficient colorimetric detection of target cancer cells.

Dalton Trans. 44 , 12871-7, (2015)

The catalytic activity of nanocrystal catalysts depends strongly on their chemical composition, size, and shape. Herein, we report four different sizes and shapes of MnFe2O4 nanoparticles (NPs) prepar...

Synonyms

Acetylacetone Manganese(II) Salt
2,4-Pentanedione manganese(II) derivative,Manganous acetylacetonate,Mn(acac)2
Manganese(II) Acetylacetonate Dihydrate
EINECS 237-858-2
Manganese(II) Acetyllacetonate
2,4-Pentanedione manganese(II) derivative
2,4-Pentanedione, manganese salt (2:1)
Manganese(II) acetylacetonate
Manganese(II) bis(acetylacetonate)
Acetylacetone Manganese(II) Salt Dihydrate
MFCD00000022
2,4-Pentanedione - manganese (2:1)
CAS 941908-19-6|1-(4-(4-Methoxybenzo[d]thiazol-2-yl)piperazin-1-yl)-2-((4-methoxyphenyl)sulfonyl)eth
CAS 941901-99-1|1-(4-(4-Fluorobenzo[d]thiazol-2-yl)piperazin-1-yl)-2-((4-methoxyphenyl)sulfonyl)etha
Recommended......
TOP