CAS 14024-58-9|2,4-Pentanedione-manganese (2:1)
| Common Name | 2,4-Pentanedione-manganese (2:1) | ||
|---|---|---|---|
| CAS Number | 14024-58-9 | Molecular Weight | 255.170 |
| Density | 1.6 g/cm3 | Boiling Point | 138.4ºC at 760 mmHg |
| Molecular Formula | C10H16MnO4 | Melting Point | 180ºC |
| MSDS | ChineseUSA | Flash Point | 43.1ºC |
| Symbol | GHS07, GHS08 | Signal Word | Warning |
Names
| Name | Bis(2,4-pentanedionato)manganese(II) Dihydrate |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 1.6 g/cm3 |
|---|---|
| Boiling Point | 138.4ºC at 760 mmHg |
| Melting Point | 180ºC |
| Molecular Formula | C10H16MnO4 |
| Molecular Weight | 255.170 |
| Flash Point | 43.1ºC |
| Exact Mass | 255.042908 |
| PSA | 68.28000 |
| LogP | 1.10900 |
| Vapour Pressure | 0.174mmHg at 25°C |
| InChIKey | VNNDVNZCGCCIPA-UHFFFAOYSA-N |
| SMILES | CC(=O)C=C(C)O.CC(=O)C=C(C)O.[Mn] |
| Stability | hygroscopic |
| Water Solubility | 11.5g/l | Soluble in water |
Toxicological Information
CHEMICAL IDENTIFICATION |
ACUTE TOXICITY DATA - TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1200 mg/kg/26W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Tumorigenic - tumors at site of application
- REFERENCE :
- JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 60,1171,1978
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1350 mg/kg/21W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Musculoskeletal - tumors Tumorigenic - tumors at site of application
- REFERENCE :
- NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. (San Francisco, CA 94117) Volume(issue)/page/year: PH43-64-886 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
Safety Information
| Symbol | GHS07, GHS08 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H302 + H312 + H332-H315-H319-H335-H351 |
| Precautionary Statements | P261-P280-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xn: Harmful; |
| Risk Phrases | R20/21/22 |
| Safety Phrases | S26;S36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
| RTECS | OO9350000 |
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Synonyms
| Acetylacetone Manganese(II) Salt |
| 2,4-Pentanedione manganese(II) derivative,Manganous acetylacetonate,Mn(acac)2 |
| Manganese(II) Acetylacetonate Dihydrate |
| EINECS 237-858-2 |
| Manganese(II) Acetyllacetonate |
| 2,4-Pentanedione manganese(II) derivative |
| 2,4-Pentanedione, manganese salt (2:1) |
| Manganese(II) acetylacetonate |
| Manganese(II) bis(acetylacetonate) |
| Acetylacetone Manganese(II) Salt Dihydrate |
| MFCD00000022 |
| 2,4-Pentanedione - manganese (2:1) |
