CAS 68414-18-6|Adenosine 5′-diphosphoribose sodium

Introduction:Basic information about CAS 68414-18-6|Adenosine 5′-diphosphoribose sodium, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NameAdenosine 5′-diphosphoribose sodium
CAS Number68414-18-6Molecular Weight581.29800
Density/Boiling Point/
Molecular FormulaC15H22N5NaO14P2Melting Point/
MSDSChineseUSAFlash Point/
Symbol
GHS07
Signal WordWarning

Names

Name[[5-(6-aminopurin-9-yl)-3,4-dihydroxyoxolan-2-yl]methoxy-hydroxyphosphoryl] (2,3,4-trihydroxy-5-oxopentyl) hydrogen phosphate,sodium
SynonymMore Synonyms

Adenosine 5′-diphosphoribose sodium BiologicalActivity

DescriptionAdenosine 5′-diphosphoribose sodium (ADP ribose sodium) is a nicotinamide adenine nucleotide (NAD+) metabolite. Adenosine 5′-diphosphoribose sodium is the most potent and primary intracellular Ca2+-permeable cation TRPM2 channel activator. Adenosine 5′-diphosphoribose sodium also can enhance autophagy[1][2].
Related CatalogSignaling Pathways >>Membrane Transporter/Ion Channel >>TRP ChannelResearch Areas >>EndocrinologySignaling Pathways >>Autophagy >>AutophagyResearch Areas >>Metabolic Disease
Target

TRPM2 channel[1][2] Autophagy[1]

In VitroIn mouse embryonic fibroblasts (MEFs), H2O2 treatment demonstrates that the activation of poly(ADP-ribose) (PAR) polymerase-1 (PARP-1) produced Adenosine 5′-diphosphoribose (ADP ribose), which is an activating signal for TRPM2 channels, thereby promoting Ca2+ elevation through extracellular Ca2+ influx and (or) lysosomal Ca2+ release. This process eventually activates early or late autophagy in response to different degrees of oxidative stress[1][1]. TRPM2 channels are activated by binding of Adenosine 5′-diphosphoribose (ADP ribose) to the intracellular NUDT9-homology (NUDT9-H) domain unique to TRPM2 and located at its C terminus. In addition to ADPR, intracellular Ca2+ is an essential coactivator: TRPM2 channels open only in the combined presence of both ligands[2].
References

[1]. Zhang DX, et al. The potential regulatory roles of NAD(+) and its metabolism in autophagy. Metabolism. 2016 Apr;65(4):454-62.

[2]. Tóth B, et al. Pore collapse underlies irreversible inactivation of TRPM2 cation channel currents. Proc Natl Acad Sci U S A. 2012 Aug 14;109(33):13440-5.

Chemical & Physical Properties

Molecular FormulaC15H22N5NaO14P2
Molecular Weight581.29800
Exact Mass581.05400
PSA313.97000
InChIKeyRJWGZGBNLLYUJC-KAXKLPFCSA-M
SMILESNc1ncnc2c1ncn2C1OC(COP(=O)(O)OP(=O)([O-])OCC(O)C(O)C(O)C=O)C(O)C1O.[Na+]
Storage condition-20°C

Safety Information

Symbol
GHS07
Signal WordWarning
Hazard StatementsH315-H319-H335
Precautionary StatementsP261-P305 + P351 + P338
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Gloves
Hazard CodesXi
Risk PhrasesR36/37/38
Safety PhrasesS26;S36
RIDADRNONH for all modes of transport

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Synonyms

Adenosine 5'-diphosphoribose sodium salt
Adenosine 5 inverted exclamation marka-diphosphoribose sodium salt
MFCD00136017
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