CAS 38078-09-0|Diethylaminosulfur trifluoride
Introduction：Basic information about CAS 38078-09-0|Diethylaminosulfur trifluoride, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | Diethylaminosulfur trifluoride | ||
|---|---|---|---|
| CAS Number | 38078-09-0 | Molecular Weight | 161.189 |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 163.7±9.0 °C at 760 mmHg |
| Molecular Formula | C4H10F3NS | Melting Point | / |
| MSDS | ChineseUSA | Flash Point | 23.9±0.0 °C |
| Symbol | GHS02, GHS05, GHS07 | Signal Word | Danger |
Names
| Name | Diethylaminosulfur trifluoride |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 1.1±0.1 g/cm3 |
|---|---|
| Boiling Point | 163.7±9.0 °C at 760 mmHg |
| Molecular Formula | C4H10F3NS |
| Molecular Weight | 161.189 |
| Flash Point | 23.9±0.0 °C |
| Exact Mass | 161.048599 |
| PSA | 28.54000 |
| LogP | 2.70130 |
| Vapour Pressure | 2.0±0.3 mmHg at 25°C |
| Index of Refraction | 1.377 |
| InChIKey | CSJLBAMHHLJAAS-UHFFFAOYSA-N |
| SMILES | CCN(CC)S(F)(F)F |
| Storage condition | 2-8°C |
| Water Solubility | decomposes |
Safety Information
| Symbol | GHS02, GHS05, GHS07 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H226-H302 + H312 + H332-H314 |
| Supplemental HS | Reacts violently with water. |
| Precautionary Statements | P280-P305 + P351 + P338-P310 |
| Personal Protective Equipment | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | C:Corrosive; |
| Risk Phrases | R10;R14;R35;R5 |
| Safety Phrases | S16-S26-S36/37/39-S45 |
| RIDADR | UN 2920 8/PG 1 |
| WGK Germany | 3 |
| Packaging Group | I |
| Hazard Class | 8 |
| HS Code | 2930909090 |
Customs
| HS Code | 2930909090 |
|---|---|
| Summary | 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
Articles31
More Articles| Rearrangement of homoallylic alcohols induced by DAST. Org. Lett. 8 , 2091, (2006) [reaction: see text] Treatment of beta,gamma-unsaturated monoprotected 1,2-diols with diethylaminosulfur trifluoride (DAST) allows the stereoselective formation of beta,gamma-unsaturated aldehydes in ... | |
| Fluorinative Beckmann fragmentation: fluorinative alpha-cleavage of cyclic ketoximes by diethylaminosulfur trifluoride. Chem. Pharm. Bull. 48(2) , 220-2, (2000) Diethylaminosulfur trifluoride reacted with cyclic ketoximes bearing substituent(s) that can stabilize a carbocation to cause fluorinative fragmentation, affording fluorinated carbonitrile. Ketoximes ... | |
| Synthesis of functionalized oxazolines and oxazoles with DAST and Deoxo-Fluor. Org. Lett. 2(8) , 1165-8, (2000) [formula: see text] A mild and highly efficient cyclization of beta-hydroxy amides to oxazolines is described using DAST and Deoxo-Fluor reagents. A one-pot protocol for the synthesis of oxazoles from... |
Synonyms
| DAST |
| diethylaminosulfurtrifluoride |
| N-ethyl-N-(trifluoro-λ<sup>4</sup>-sulfanyl)ethanamine |
| Sulfur, (diethylamino)trifluoro- |
| N-Ethyl-N-(trifluoro-λ-sulfanyl)ethanamine |
| Diethylaminosulfur trifluoride |
| (Diethylamino)sulfur trifluoride |
| Sulfur Trifluoride Diethylamine Complex |
| (Diethylamino)sulfur Trifluoride (DAST) |
| EINECS 253-771-2 |
| [Ethyl(trifluor-λ-sulfanyl)amino]ethan |
| UNII-78622BV6IJ |
| Diethylaminosulphur trifluoride |
| MFCD00000363 |
| (DIETHYLAMINO)SULPHUR TRIFLUORIDE |
