CAS 15529-49-4|Dichlororuthenium-triphenylphosphine (1:3)

Introduction:Basic information about CAS 15529-49-4|Dichlororuthenium-triphenylphosphine (1:3), including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NameDichlororuthenium-triphenylphosphine (1:3)
CAS Number15529-49-4Molecular Weight958.832
Density/Boiling Point360ºC at 760 mmHg
Molecular FormulaC54H45Cl2P3RuMelting Point159 °C
MSDSChineseUSAFlash Point181.7ºC
Symbol
GHS07
Signal WordWarning

Names

NameTris(Triphenylphosphine)Ruthenium(II) Chloride
SynonymMore Synonyms

Chemical & Physical Properties

Boiling Point360ºC at 760 mmHg
Melting Point159 °C
Molecular FormulaC54H45Cl2P3Ru
Molecular Weight958.832
Flash Point181.7ºC
Exact Mass958.115479
PSA40.77000
LogP11.71340
Vapour Pressure4.74E-05mmHg at 25°C
InChIKeyWIWBLJMBLGWSIN-UHFFFAOYSA-L
SMILESCl[Ru]Cl.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1
Storage conditionRefrigerator
Water Solubilityinsoluble

Safety Information

Symbol
GHS07
Signal WordWarning
Hazard StatementsH302 + H312 + H332
Precautionary StatementsP280
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Gloves
Hazard CodesXn:Harmful;
Risk PhrasesR20/21
Safety PhrasesS36/37-S22
RIDADRNONH for all modes of transport
WGK Germany3

Articles2

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Cross-coupling reaction between alcohols through sp3 C-H activation catalyzed by a ruthenium/Lewis acid system.

Chemistry 33th ed., 14 , 10201-10205, (2008)

Synonyms

Dichlorotris(triphenylphosphine)ruthenium(II)
Ruthenium(2+) chloride triphenylphosphine (1:2:3)
Tris(triphenylphosphine)ruthenium(II) dichloride
Dichlororuthenium - triphenylphosphine (1:3)
Phosphine, triphenyl-, ruthenium(2+) salt, hydrochloride (3:1:2)
EINECS 239-569-7
Dichlorotris(triphenylphosphino)ruthenium (II)
MFCD00013077
Tris(triphenylphosphine)ruthenium(II) chloride
Tris(triphenylphosphine)ruthenium(II)chloride
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