CAS 3544-24-9|3-Aminobenzamide

Introduction:Basic information about CAS 3544-24-9|3-Aminobenzamide, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Name3-Aminobenzamide
CAS Number3544-24-9Molecular Weight136.151
Density1.2±0.1 g/cm3Boiling Point329.6±25.0 °C at 760 mmHg
Molecular FormulaC7H8N2OMelting Point115-116 °C(lit.)
MSDSChineseUSAFlash Point153.2±23.2 °C
Symbol
GHS07
Signal WordWarning

Names

Name3-aminobenzamide
SynonymMore Synonyms

3-Aminobenzamide BiologicalActivity

Description3-Aminobenzamide is a potent inhibitor of PARP with IC50 of appr 50 nM in CHO cells, and acts as a mediator of oxidant-induced myocyte dysfunction during reperfusion.
Related CatalogResearch Areas >>Cancer
Target

PARP:50 nM (IC50)

In Vitro3-Aminobenzamide (>1 μM) causes more than 95% inhibition of PARP activity without significant cellular toxicity. INO-1001 significantly sensitizes CHO cells by blocking most of the DNA repair occurring between radiation fractions[1]. 3-Aminobenzamide significantly improves endothelial function by enhancing the acetylcholine-induced, endothelium-dependent, nitric oxide mediated vasorelaxation after exposure with 400 μM H2O2[2].
In VivoIn a db/db (Leprdb/db) mouse model, 3-Aminobenzamide ameliorates diabetes-induced albumin excretion and mesangial expansion, and also decreases diabetes-induced podocyte depletion[3]. 3-Aminobenzamide (1.6 mg/kg via intracerebral injection) prevents NAD+ depletion and improves water maze performance after controlled cortical impact (CCI) in mice[4].
Kinase AssayPARP activity is measured with a PARP Activity Assay Kit. This method measures relative PARP activity by determining the level of incorporation of 3H-NAD into trichloroacetic acid (TCA) precipitable material in the presence of sheared genomic DNA, which activates PARP. The reaction mixture is added directly to washed cultures in 12-well culture plates and the reaction is allowed to proceed for 60 minutes at 37°C before the cells are removed mechanically, transferred to a microcentrifuge tube, and precipitated with ice-cold 5% TCA.
Animal AdminMale db/db (Leprdb/db) mice, together with nondiabetic control db/m mice on C57BLKs/J background, are used. INO-1001 and PJ-34 treatment are initiated at 5 weeks of age. In sterile water that is sweetened with NutraSweet, 4.8 g/L 3-Aminobenzamide and 2.4 g/L PJ-34 is dissolved. Control animals receive sweetened water only. The average inhibitor consumption is 60 mg/kg 3-Aminobenzamide and 30 mg/kg PJ-34.
References

[1]. Brock WA, et al. Radiosensitization of human and rodent cell lines by INO-1001, a novel inhibitor of poly(ADP-ribose) polymerase. Cancer Lett. 2004 Mar 18;205(2):155-60.

[2]. Radovits T, et al. Poly(ADP-ribose) polymerase inhibition improves endothelial dysfunction induced by reactive oxidant hydrogen peroxide in vitro. Eur J Pharmacol. 2007 Jun 14;564(1-3):158-66.

[3]. Szabo C, et al. Poly(ADP-ribose) polymerase inhibitors ameliorate nephropathy of type 2 diabetic Leprdb/db mice. Diabetes. 2006 Nov;55(11):3004-12.

[4]. Clark RS, et al. Local administration of the poly(ADP-ribose) polymerase inhibitor INO-1001 prevents NAD+ depletion and improves water maze performance after traumatic brain injury in mice. J Neurotrauma. 2007 Aug;24(8):1399-405.

Chemical & Physical Properties

Density1.2±0.1 g/cm3
Boiling Point329.6±25.0 °C at 760 mmHg
Melting Point115-116 °C(lit.)
Molecular FormulaC7H8N2O
Molecular Weight136.151
Flash Point153.2±23.2 °C
Exact Mass136.063660
PSA69.11000
LogP0.33
Vapour Pressure0.0±0.7 mmHg at 25°C
Index of Refraction1.633
InChIKeyGSCPDZHWVNUUFI-UHFFFAOYSA-N
SMILESNC(=O)c1cccc(N)c1
Water Solubilityethanol: 50 mg/mL, clear, faintly yellow

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CU8992000
CHEMICAL NAME :
Benzamide, m-amino-
CAS REGISTRY NUMBER :
3544-24-9
BEILSTEIN REFERENCE NO. :
2802373
LAST UPDATED :
199612
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C7-H8-N2-O
MOLECULAR WEIGHT :
136.17
WISWESSER LINE NOTATION :
ZVR CZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - wild bird species
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Mammal - species unspecified Fibroblast
DOSE/DURATION :
1 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 254,13,1991

Safety Information

Symbol
GHS07
Signal WordWarning
Hazard StatementsH302-H315-H319-H335
Precautionary StatementsP280-P301 + P312 + P330-P304 + P340 + P312-P305 + P351 + P338-P337 + P313
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Gloves
Hazard CodesXi:Irritant;
Risk PhrasesR36/37/38
Safety PhrasesS26-S36-S37/39
RIDADRNONH for all modes of transport
WGK Germany3
RTECSCU8992000
HS Code2924299090

Customs

HS Code2924299090
Summary2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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Synonyms

meta-aminobenzoylamine
m-Aminobenzamide
3-Aminobenzimide
Benzamide,m-amino
Benzamide, 3-amino-
3-Aminobenzamide
3-Amino-benzamide
MFCD00007989
EINECS 222-586-9
Benzamide,3-amino
INO1001
meta-aminobenzamide
3-NH2-Ph-CO-NH2
5-amino-benzamide
INO-1001
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