(1S)-(1)-beta-Pinene CAS 18172-67-3
Introduction：Basic information about (1S)-(1)-beta-Pinene CAS 18172-67-3, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
(1S)-(1)-beta-Pinene Basic information
| Product Name: | (1S)-(1)-beta-Pinene |
| Synonyms: | FEMA 2903;(1S)-(-)-BETA-PINENE 97+% FCC;(-)-Pinene, 99+% (97% EE/GLC);Bicyclo3.1.1heptane, 6,6-dimethyl-2-methylene-, (1S,5S)-;(1s)-(-)-á-pinene;ALPHA,BETA-PINENE;Bicyclo[3.1.1]heptanie, 6,6-dimethyl-2-methylene-, (1S)-;(1S)-(-)-SS-PINENE |
| CAS: | 18172-67-3 |
| MF: | C10H16 |
| MW: | 136.23 |
| EINECS: | 242-060-2 |
| Product Categories: | Industrial/Fine Chemicals |
| Mol File: | 18172-67-3.mol |
(1S)-(1)-beta-Pinene Chemical Properties
| Melting point | −61 °C(lit.) |
| alpha | -18.5 º (c=neat 25 ºC) |
| Boiling point | 165-167 °C(lit.) |
| density | 0.866 g/mL at 25 °C |
| vapor density | 4.7 (vs air) |
| vapor pressure | ~2 mm Hg ( 20 °C) |
| refractive index | n |
| FEMA | 2903 | BETA-PINENE |
| Fp | 91 °F |
| storage temp. | 2-8°C |
| solubility | 95% ethanol: soluble1ml/3ml, clear, colorless |
| form | Liquid |
| color | Clear colorless to pale yellow |
| Odor | at 10.00 % in dipropylene glycol. dry woody fresh pine hay green resinous |
| Odor Type | herbal |
| Odor Threshold | 0.033ppm |
| biological source | synthetic |
| Optical Rotation | [α]25/D 22°, neat |
| Water Solubility | insoluble |
| Merck | 14,7446 |
| BRN | 2038282 |
| Cosmetics Ingredients Functions | PERFUMING |
| InChI | 1S/C10H16/c1-7-4-5-8-6-9(7)10(8,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9-/m0/s1 |
| InChIKey | WTARULDDTDQWMU-IUCAKERBSA-N |
| SMILES | [H][C@]12CCC(=C)[C@]([H])(C1)C2(C)C |
| LogP | 4.4 at 25℃ |
| CAS DataBase Reference | 18172-67-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene-, (1S)-(18172-67-3) |
| EPA Substance Registry System | (-)-.beta.-Pinene (18172-67-3) |
Safety Information
| Hazard Codes | Xn,N,Xi |
| Risk Statements | 10-20/21/22-36/37/38-43-51-65-51/53-50 |
| Safety Statements | 16-26-36/37-46-61-62 |
| RIDADR | UN 2319 3/PG 3 |
| WGK Germany | 3 |
| RTECS | DT5077000 |
| TSCA | TSCA listed |
| HazardClass | 3 |
| PackingGroup | III |
| HS Code | 29021910 |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Aquatic Acute 1 Aquatic Chronic 1 Asp. Tox. 1 Flam. Liq. 3 Skin Irrit. 2 Skin Sens. 1 |
| Description | (–)-β-Pinene is a bicyclic monoterpene that has been found in various plants, including C. sativa, with diverse biological activities. It is lethal to S. littoralis third instar larvae (LD50 = 65 μg/larva). (–)-β-Pinene inhibits infectious bronchitis virus (IBV) replication (IC50 = 1.32 mM) and exhibits a cytotoxic concentration (CC50) value of greater than 10 mM in Vero cells. In vivo, (–)-β-pinene (100 mg/kg) decreases immobility time in the forced swim test in mice, an effect that can be reversed by the serotonin (5-HT) receptor subtype 5-HT1A antagonist WAY-100635 . |
| Chemical Properties | clear colorless to pale yellow liquid |
| Uses | It is a useful biochemical for proteomics research. It is also employed in the preparation of natural products, such as grandisol and robustadial. It is also applied as perfuming agent in cosmetics industry. |
| Uses | (-)-β-Pinene has been used as a standard for the analysis of terpenoid compounds in plant essential oils by GC analysis. It may be used as a building block to synthesize natural products such as grandisol, robustadial and (+)-nopinone. (-)-β-Pinene undergoes hydroformylation in the presence of platinum/tin catalysts to form trans-10-formylpinane. |
| Definition | ChEBI: (-)-beta-pinene is the (1S,5S)-enantiomer of beta-pinene. It is an enantiomer of a (+)-beta-pinene. |
| References | [1] M. NIGAM. ESSENTIAL OILS AND THEIR CONSTITUENTS: XXIX. THE ESSENTIAL OIL OF MARIHUANA: COMPOSITION OF GENUINE INDIAN CANNABIS SATIVA L.[J]. Canadian Journal of Chemistry, 1965, 48 1: 3372-3376. DOI: 10.1139/v65-468 [2] ZHIWEI YANG. Comparative anti-infectious bronchitis virus (IBV) activity of (-)-pinene: effect on nucleocapsid (N) protein.[J]. Molecules, 2011, 16 2: 1044-1054. DOI: 10.3390/molecules16021044 [3] SILVIA LAURA GUZMáN-GUTIéRREZ . Linalool and β-pinene exert their antidepressant-like activity through the monoaminergic pathway[J]. Life sciences, 2015, 128: Pages 24-29. DOI: 10.1016/j.lfs.2015.02.021 |
(1S)-(1)-beta-Pinene Preparation Products And Raw materials
| Preparation Products | 1,3-Methanonaphthalen-5(1H)-one, 2,3,4,6,7,8-hexahydro-2,2-dimethyl- |
