Introduction：Basic information about (S)-4-Benzyl-2-oxazolidinone CAS 90719-32-7, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
(S)-4-Benzyl-2-oxazolidinone Basic information
| Product Name: | (S)-4-Benzyl-2-oxazolidinone |
| Synonyms: | (4S)-4-BENZYL-1,3-OXAZOLIDIN-2-ONE;4-S-BENZYL-OXAZOLIDIN-2-ONE;(S)-(-)-4-BENZYL-2-OXAZOLIDINONE;(S)-4-BENZYL-2-OXAZOLIDINONE;(S)-(-)-4-BENZYL-2-OXAZOLIDONE;(S)-4-Benzyl-2-oxazolodinone, 99% ee:>99%;2-OXAZOLIDINONE, 4-(PHENYLMETHYL)-, (4S)-;(S)-4-Benzyl-2-oxazolidinone, >99% ee |
| CAS: | 90719-32-7 |
| MF: | C10H11NO2 |
| MW: | 177.2 |
| EINECS: | 618-632-6 |
| Product Categories: | Asymmetric Synthesis;Chiral Auxiliaries;Oxazolidinone Derivatives;Oxazolidinone;Chiral Compounds;chiral;Aromatics Compounds;Asymmetric Synthesis;Chiral Building Blocks;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry;Chiral chemicals;Peptide;Aromatics;Chiral Reagents;Heterocycles;aliskiren;90719-32-7 |
| Mol File: | 90719-32-7.mol |
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(S)-4-Benzyl-2-oxazolidinone Chemical Properties
| Melting point | 86-88 °C(lit.) |
| alpha | -62 º (C=1, CHCl3) |
| Boiling point | 309.12°C (rough estimate) |
| density | 1.1607 (rough estimate) |
| refractive index | -14.5 ° (C=5, MeOH) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| pka | 12.78±0.40(Predicted) |
| form | Crystalline Powder |
| color | White to very slightly yellow |
| Optical Rotation | [α]20/D 63°, c = 1 in chloroform |
| Water Solubility | Insoluble in water. |
| Sensitive | Hygroscopic |
| BRN | 3649667 |
| InChI | 1S/C10H11NO2/c12-10-11-9(7-13-10)6-8-4-2-1-3-5-8/h1-5,9H,6-7H2,(H,11,12)/t9-/m0/s1 |
| InChIKey | OJOFMLDBXPDXLQ-VIFPVBQESA-N |
| SMILES | O=C1N[C@H](CO1)Cc2ccccc2 |
| CAS DataBase Reference | 90719-32-7(CAS DataBase Reference) |
Safety Information
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 24/25-36-26-37/39 |
| WGK Germany | 3 |
| F | 3-10 |
| HS Code | 29349990 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Acute Tox. 4 Oral
STOT RE 2 |
(S)-4-Benzyl-2-oxazolidinone Usage And Synthesis
| Chemical Properties | white to light yellow crystal powde |
| Uses | (S)-(-)-4-Benzyl-2-oxazolidinone is used in chiral auxiliary asymmetric alkylation. It has been used in the synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides. It was used for asymmetric synthesis of (3R)- and (3S)-piperazic acid. |
| Uses | As an oxazolidinone, (S)-4-Benzyl-2-Oxazolidinone can be used in chiral auxiliary asymetric synthesis. |
| Definition | ChEBI: (S)-4-BENZYL-2-OXAZOLIDINONE is a member of benzenes. |
(S)-4-Benzyl-2-oxazolidinone Preparation Products And Raw materials
| Preparation Products | 4-Benzyl-2-oxo-oxazolidine-3-carbonyl chloride-->(S)-4-Benzyl-3-propionyl-2-oxazolidinone-d3-->(S)-4-benzyl-3-(5,5,5-trifluoropentanoyl)oxazolidin-2-one |
