1,1,1-TRIMETHYLHYDRAZINIUM IODIDE CAS 3288-80-0

Introduction：Basic information about 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE CAS 3288-80-0, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Basic information

• Product Name: 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
• Synonyms: 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE;1,1,1-TRIMETHYLHYDRAZONIUM IODIDE;1,1,1-trimethyl-hydraziniuiodide;1,1,1-trimethyl-hydrazoniuiodide;1,1,1-triMethylhydrazin-1-iuM iodide;1,1,1-TriMethylhydraziniuM iodide 97%;Mildronate Impurity 1;amino(trimethyl)azanium:iodide
• CAS: 3288-80-0
• MF: C3H11IN2
• MW: 202.04
• Product Categories: Hydrazines;Nitrogen Compounds;Organic Building Blocks
• Mol File: 3288-80-0.mol

1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Chemical Properties

• Melting point: 225-230 °C (dec.) (lit.)
• storage temp.: 2-8°C, sealed storage, away from moisture and light
• Appearance: White to off-white Solid
• InChI: 1S/C3H11N2.HI/c1-5(2,3)4;/h4H2,1-3H3;1H/q+1;/p-1
• InChIKey: HLNPDVKKRBWQAA-UHFFFAOYSA-M
• SMILES: [I-].C[N+](C)(C)N
• EPA Substance Registry System: 1,1,1-trimethylhydrazinium iodide (3288-80-0)

Safety Information

• Hazard Codes: T
• Risk Statements: 61-36/37/38
• Safety Statements: 53-36/37/39-45
• WGK Germany: 3
• RTECS: MW0349100
• TSCA: TSCA listed
• HS Code: 2928009090
• Storage Class: 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
• Hazard Classifications: Eye Irrit. 2 Repr. 1B Skin Irrit. 2 STOT SE 3

1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Usage And Synthesis

Uses

1,1,1-Trimethylhydrazinium iodide (TMHI) may be employed for the amination of 1-X-3,5-dinitrobenzenes.

General Description

1,1,1-Trimethylhydrazinium iodide ([(CH₃)₃N-NH₂]I, TMHI) is widely employed as a vicarious nucleophilic substitution (VNS) reagent for various aromatic amination reactions. On reaction with silver salt, it affords the following salts: nitrate (([(CH₃)₃N-NH₂][NO₃]), perchlorate ([(CH₃)₃N-NH₂][ClO₄]), azide ([(CH₃)₃N-NH₂][N₃]), 5-amino-1H-tetrazolate ([(CH₃)₃N-NH₂][H₂N-CN₄]) and sulfate ([(CH₃)₃N-NH₂]₂[SO₄].2H₂O).