Introduction：Basic information about 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE CAS 498-07-7, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Basic information
| Product Name: | 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE |
| Synonyms: | 1,6-Anhydro-D-glucopyranose, 99℉;1,6-Anhydro-beta-D-glucopyranose, 99+%;1,6-Anhydro-b-D-glucopyranose;1,6-anhydro-á-d-glucopyranose;1,6-anhydro-beta-glucopyranose;1,6-ANHYDRO-BETA-D-GLUCOPYRA;1,6-ANHYDRO-SS-D-GLUCOPYRANOSE;1,6-Dideoxy-1,6-epoxy-β-D-glucopyranose |
| CAS: | 498-07-7 |
| MF: | C6H10O5 |
| MW: | 162.14 |
| EINECS: | 207-855-0 |
| Product Categories: | O-Substituted Sugars;Biochemistry;Glucose;Sugars;Carbohydrates & Derivatives;Sugars, Carbohydrates & Glucosides;Glycon Biochem |
| Mol File: | 498-07-7.mol |
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1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Chemical Properties
| Melting point | 182-184 °C(lit.) |
| alpha | -66 º (C=1 IN H2O) |
| Boiling point | 208.81°C (rough estimate) |
| density | 1.2132 (rough estimate) |
| refractive index | -66.5 ° (C=2, H2O) |
| storage temp. | 2-8°C |
| solubility | Methanol (Slightly), Water (Sparingly) |
| pka | 13.40±0.60(Predicted) |
| form | Crystalline Powder or Crystals |
| color | White to slightly beige |
| Optical Rotation | [α]18/D 66°, c = 1 in H2O |
| Water Solubility | Soluble in Ethanol and Water. |
| BRN | 80998 |
| Stability: | Hygroscopic |
| Major Application | food and beverages |
| InChI | 1S/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2/t2-,3-,4+,5-,6-/m1/s1 |
| InChIKey | TWNIBLMWSKIRAT-VFUOTHLCSA-N |
| SMILES | O[C@H]1[C@H](O)[C@H]2CO[C@H](O2)[C@@H]1O |
| LogP | -1.694 (est) |
| NIST Chemistry Reference | 1,6-Anhydro-beta-D-glucopyranose(498-07-7) |
| EPA Substance Registry System | .beta.-D-Glucopyranose, 1,6-anhydro- (498-07-7) |
Safety Information
| Hazard Codes | Xn |
| Risk Statements | 20/21/22-36/37/38 |
| Safety Statements | 22-24/25-36-26 |
| WGK Germany | 3 |
| HS Code | 29400000 |
| Storage Class | 11 - Combustible Solids |
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Usage And Synthesis
| Chemical Properties | White Crystalline Odourless Solid |
| Uses | 1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars. |
| Uses | 1,6-Anhydro-β-D-glucose is an useful carbohydrate synthon pharmaceutical intermediate. |
| Uses | 1,6-Anhydro-beta-D-glucopyranose is used for the preparation of biologically important and structurally diverse products such as rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, macrolide antibiotics and modified sugars. It is used as a chemical tracer for biomass burning in atmospheric chemistry studies, particularly with respect to airborne particulate matter. It aids in the production of bioethanol. |
| Definition | ChEBI: A anhydrohexose that is the 1,6-anhydro-derivative of beta-D-glucopyranose. |
| General Description | 1,6-Anhydro-β-D-glucose (Levoglucosa), belonging to the class of anhydrosugars, is an indicator of the burning of biomass in atmospheric aerosol, snow, and ice. It is formed via pyrolysis of glucans, such as cellulose and starch. Levoglucosa is also found in municipal waste and thermochemical processing products of biomass and soil. |
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Preparation Products And Raw materials
| Preparation Products | β-D-Glucopyranose, 1,6-anhydro-2,3,4-tris-O-(trimethylsilyl)- |
