Introduction：Basic information about 2-Allyloxyethanol CAS 111-45-5, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
2-Allyloxyethanol Basic information
| Product Name: | 2-Allyloxyethanol |
| Synonyms: | 2-(2-propenyloxy)-ethano;2-Prop-2-enoxyethanol;2-Allyloxyethyl alcohol;2-Allyloxyethanol,Ethylene glycol allyl ether;Allyl Glycol2-Allyloxyethanol;Ethylene glycol monallyl ether;EGMAE;2-Allyloxyethanole |
| CAS: | 111-45-5 |
| MF: | C5H10O2 |
| MW: | 102.13 |
| EINECS: | 203-871-7 |
| Product Categories: | ester series;Ethylene Glycols & Monofunctional Ethylene Glycols;Monofunctional Ethylene Glycols |
| Mol File: | 111-45-5.mol |
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2-Allyloxyethanol Chemical Properties
| Boiling point | 159 °C(lit.) |
| density | 0.955 g/mL at 25 °C(lit.) |
| vapor pressure | 1.842hPa at 25℃ |
| refractive index | n20/D 1.436(lit.) |
| Fp | 150 °F |
| storage temp. | 2-8°C |
| solubility | Completely miscible in water |
| form | clear liquid |
| pka | 14.50±0.10(Predicted) |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.955 |
| Odor | mild mushroom |
| Water Solubility | 454g/L at 25℃ |
| InChI | 1S/C5H10O2/c1-2-4-7-5-3-6/h2,6H,1,3-5H2 |
| InChIKey | GCYHRYNSUGLLMA-UHFFFAOYSA-N |
| SMILES | C=CCOCCO |
| LogP | -0.12 at 20℃ |
| CAS DataBase Reference | 111-45-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Ethanol, 2-(2-propenyloxy)-(111-45-5) |
| EPA Substance Registry System | Ethanol, 2-(2-propenyloxy)- (111-45-5) |
Safety Information
| Hazard Codes | Xi |
| Risk Statements | 38-41-36/37/38 |
| Safety Statements | 26-39-45-36/37/39 |
| RIDADR | NA 1993 / PGIII |
| WGK Germany | 2 |
| RTECS | KJ5425000 |
| TSCA | TSCA listed |
| HazardClass | 3 |
| PackingGroup | III |
| HS Code | 29094990 |
| Storage Class | 10 - Combustible liquids |
| Hazard Classifications | Eye Dam. 1
Skin Irrit. 2 |
2-Allyloxyethanol Usage And Synthesis
| Chemical Properties | Colorless transparent liquid |
| Uses | 2-allyloxyethanol could synthesize a new ester (Las9) with lasalocid. Las9 could form complexes with LiC, NaC, KC, RbC, and CsC cations. 2-allyloxyethanol could be used as an end-capping reagent to synthesize 2-allyloxyethanol-terminated polyurethane which is a modifier of polyurethane-modified polydimethylsiloxane (PUMS) coating[1-2]. |
| Preparation | 2-allyloxyethanol is produced from Allyl alcohol and Ethylene under pressure and in the presence of a catalyst. |
| Flammability and Explosibility | Flammable |
| Solubility in organics | Soluble in alcohol and oils. |
| References | [1] Rados?aw Pankiewicz, Bogumil Brzezinski, Grzegorz Schroeder. “Spectroscopic and PM5 semiempirical study of a new lasalocid ester with 2-allyloxyethanol and its complexes with monovalent cations.” Journal of Molecular Structure 789 1 (2006): Pages 1-7.
[2] Zhe Sun . “Polyurethane covalently modified polydimethylsiloxane (PDMS) coating with increased surface energy and re-coatability.” Progress in Organic Coatings 146 (2020): Article 105744. |
2-Allyloxyethanol Preparation Products And Raw materials
| Preparation Products | Ethanol, 2-[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1-disiloxanyl]propoxy]--->4,7,10,13-Tetraoxahexadeca-1,15-diene |
