Introduction：Basic information about 2-Bromo-5-methoxytoluene CAS 27060-75-9, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
2-Bromo-5-methoxytoluene Basic information
| Product Name: | 2-Bromo-5-methoxytoluene |
| Synonyms: | 2-Bromo-5-methoxytoluene, 1-Bromo-4-methoxy-2-methylbenzene, 4-Bromo-3-methylphenyl methyl ether;2-BroMo-5-Methoxytoluene (BMA);4-BroMo-3-Methylanisole, 97%, 97%;2-Bromo-4-methoxy-1-methylbenzene;1-BROMO-4-METHOXY-2-METHYLBENZENE;2-BROMO-5-METHOXYTOLUENE;2-(3-bromophenyl)-2-methoxyacetic acid;3-Methyl-4-bromoanisole |
| CAS: | 27060-75-9 |
| MF: | C8H9BrO |
| MW: | 201.06 |
| EINECS: | |
| Product Categories: | Halogen toluene;Anisoles, Alkyloxy Compounds & Phenylacetates;Aromatic Hydrocarbons (substituted) & Derivatives;Bromine Compounds |
| Mol File: | 27060-75-9.mol |
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2-Bromo-5-methoxytoluene Chemical Properties
| Melting point | 16.5 °C |
| Boiling point | 111-112 °C15 mm Hg(lit.) |
| density | 1.424 g/mL at 25 °C(lit.) |
| refractive index | n20/D 1.561(lit.) |
| Fp | >230 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | water: soluble (Partially miscible)(lit.) |
| form | Liquid |
| color | Clear colorless to slightly yellow |
| Specific Gravity | 1.424 |
| Water Solubility | water: soluble (Partially miscible)(lit.) |
| FreezingPoint | 12.0 to 16.0 ℃ |
| BRN | 1933865 |
| InChI | 1S/C8H9BrO/c1-6-5-7(10-2)3-4-8(6)9/h3-5H,1-2H3 |
| InChIKey | BLZNSXFQRKVFRP-UHFFFAOYSA-N |
| SMILES | COc1ccc(Br)c(C)c1 |
| CAS DataBase Reference | 27060-75-9(CAS DataBase Reference) |
| NIST Chemistry Reference | 2-Bromo-5-methoxytoluene(27060-75-9) |
| EPA Substance Registry System | 2-Bromo-5-methoxytoluene (27060-75-9) |
Safety Information
| Hazard Codes | Xi |
| Safety Statements | 24/25 |
| WGK Germany | 3 |
| Hazard Note | Irritant |
| TSCA | TSCA listed |
| HS Code | 29093090 |
| Storage Class | 10 - Combustible liquids |
| Hazard Classifications | Acute Tox. 4 Oral |
2-Bromo-5-methoxytoluene Usage And Synthesis
| Chemical Properties | colorless to light yellow liquid |
| Uses | 2-bromo-5-methoxytoluene could be used to syntheis 4-bromo-3-(bromomethyl)anisole. In specifically, to a CCl4 solution (125 mL) of 2-bromo-5-methoxytoluene (0.050 mol) and NBS (0.055 mol) was added AIBN (0.001 mol), and the mixture was stirred at 80 °C for 18 h. The mixture was diluted with hexane before filtration through a Celite pad. Evaporation of the solvent and washing the residue with ethyl acetate gave 4-bromo-3-(bromomethyl)anisole. |
2-Bromo-5-methoxytoluene Preparation Products And Raw materials
| Raw materials | 4-METHOXY-2-METHYLBENZYL ALCOHOL-->4-Bromo-3-methylphenol-->4-BROMO-3-METHOXYPHENYL-P-TOLUENESULFONATE-->3-Methyl-4-nitroanisole-->4-METHOXY-2-METHYLBENZOIC ACID-->3-Bromo-2-methylbenzoic acid-->3-METHOXYBENZYL BROMIDE-->N-Bromosuccinimide |
| Preparation Products | 3-Methylanisole-->Methoxymethyldiphenylamine-->4-METHOXY-2-METHYLBENZONITRILE |
