9-(3-bromophenyl)carbazole CAS 185112-61-2
Introduction：Basic information about 9-(3-bromophenyl)carbazole CAS 185112-61-2, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
9-(3-bromophenyl)carbazole Basic information
| Product Name: | 9-(3-bromophenyl)carbazole |
| Synonyms: | 9-(3-bromophenyl)carbazole;9-(3-BROMOPHENYL)CARBAZOLE; N-(3-BROMOPHENYL)CARBAZOLE; 9-(3-BROMOPHENYL)-9H-CARBAZOLE;N-(3-BroMophenyl)carbazole(N3BPC);9-(3-broMophenyl)carbazole/N-(3-BroMophenyl)carbazole;N-(3-BroMophenyl)carbazole;N-(3-BroMophenyl)-9H-carbazole;9H-Carbazole, 9-(3-broMophenyl)-;NBPC |
| CAS: | 185112-61-2 |
| MF: | C18H12BrN |
| MW: | 322.2 |
| EINECS: | 807-965-4 |
| Product Categories: | |
| Mol File: | 185112-61-2.mol |
9-(3-bromophenyl)carbazole Chemical Properties
| Melting point | 69-70℃ |
| Boiling point | 463℃ |
| density | 1.39 |
| Fp | 234℃ |
| storage temp. | Sealed in dry,Room Temperature |
| form | powder to crystal |
| color | White to Almost white |
| InChI | InChI=1S/C18H12BrN/c19-13-6-5-7-14(12-13)20-17-10-3-1-8-15(17)16-9-2-4-11-18(16)20/h1-12H |
| InChIKey | ZKGHGKNHPPZALY-UHFFFAOYSA-N |
| SMILES | N1(C2=CC=CC(Br)=C2)C2=C(C=CC=C2)C2=C1C=CC=C2 |
Safety Information
| HS Code | 2933.99.8290 |
| Chemical Properties | White solid |
| Uses | 9-(3-bromophenyl)carbazole can be used to synthesize organic optoelectronic materials. |
| Hazard | 9-(3-bromophenyl)carbazole can cause skin irritation and serious eye irritation. |
| Synthesis | 1-bromo-3-iodobenzene, 2.02 mL (15.8mmol), copper (Cu) 2.29 g (36.0 mmol) of calcium carbonate and 4.98 g (36.0 mmol) of DMF in 30 mL insert heated at 130 It was stirred. After the completion of the reaction, it cooled to ambient temperature, diluted with ethyl acetate to a vacuum filter, and passed through a silica gel. The filtrate was concentrated under reduced pressure. Separating the product by silica gel column chromatography (ethyl acetate: n-hexane = 1: 20) to give 9-(3-bromophenyl)carbazole 3.80 g (98 per cent yield). |
| References | [1] Patent: KR101593182, 2016, B1. Location in patent: Paragraph 0427; 0430; 0438; 0439 [2] Patent: CN107686484, 2018, A. Location in patent: Paragraph 0123-0128 [3] Patent: KR101622443, 2016, B1. Location in patent: Paragraph 0109; 0110 [4] RSC Advances, 2015, vol. 5, # 64, p. 51512 - 51523 [5] Patent: WO2012/4765, 2012, A2. Location in patent: Page/Page column 73-74 |
9-(3-bromophenyl)carbazole Preparation Products And Raw materials
| Raw materials | 1,3-Dibromobenzene-->3-Bromofluorobenzene-->1-Bromo-3-iodobenzene-->Carbazole-->1,3-Cyclohexadiene, 5,5-dimethyl--->Copper(l) iodide-->Potassium carbonate |
| Preparation Products | 3-(9H-Carbazol-9-yl)phenylboronic acid-->(3-(carbazole-9H)Phenyl)Pinacol ester |
