Ammonium chloroplatinate CAS 16919-58-7
Introduction：Basic information about Ammonium chloroplatinate CAS 16919-58-7, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Ammonium chloroplatinate Basic information
| Product Name: | Ammonium chloroplatinate |
| Synonyms: | Ammoniumchloroplatinate(IV);ammoniumplatinicchloride;diammonium,(oc-6-11)-platinate(2-hexachloro-;diammoniumhexachloroplatinate(2-);Platinate(2-),hexachloro-, aMMoniuM (1:2), (OC-6-11)-;Ammonium hexachloroplatinate(IV) 99.999% trace metals basis;Ammonium hexachloroplatinate(Ⅳ);Pt44%Ammonium hexachloroplatinate(IV IV) |
| CAS: | 16919-58-7 |
| MF: | Cl6Pt.2H4N |
| MW: | 443.88 |
| EINECS: | 240-973-0 |
| Product Categories: | chemical reaction,pharm,electronic,materials;halometallate salt;Inorganics |
| Mol File: | 16919-58-7.mol |
Ammonium chloroplatinate Chemical Properties
| Melting point | °Cd ec.) |
| density | 3.07 g/mL at 25 °C(lit.) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | insoluble in ethanol |
| form | Powder |
| color | Yellow |
| Specific Gravity | 3.065 |
| Water Solubility | Slightly soluble in water. Insoluble in alcohol, ether and concentrated hydrochloric acid. |
| Sensitive | Hygroscopic |
| Merck | 14,548 |
| Exposure limits | ACGIH: TWA 0.002 mg/m3 NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 |
| Stability: | hygroscopic |
| InChI | InChI=1S/6ClH.2H3N.Pt/h6*1H;2*1H3;/q;;;;;;;;+4/p-4 |
| InChIKey | PCCGQTHFYHJATL-UHFFFAOYSA-J |
| SMILES | [Pt-2](Cl)(Cl)(Cl)(Cl)(Cl)Cl.[NH4+].[NH4+] |
| CAS DataBase Reference | 16919-58-7(CAS DataBase Reference) |
| EPA Substance Registry System | Ammonium chloroplatinate (16919-58-7) |
Safety Information
| Hazard Codes | T |
| Risk Statements | 25-41-42/43 |
| Safety Statements | 22-26-36/37/39-45 |
| RIDADR | UN 3288 6.1/PG 3 |
| WGK Germany | 1 |
| RTECS | BP5425000 |
| TSCA | TSCA listed |
| HazardClass | 6.1 |
| PackingGroup | III |
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
| Hazard Classifications | Acute Tox. 3 Oral Eye Dam. 1 Resp. Sens. 1 Skin Sens. 1 |
| Hazardous Substances Data | 16919-58-7(Hazardous Substances Data) |
| Toxicity | LD50 orl-rat: 195 mg/kg GTPZAB 21(7),55,77 |
| Chemical Properties | Ammonium chloroplatinate is an orange-redcrystalline cubic solid or yellow powder which decomposeswhen heated. |
| Chemical Properties | YELLOW CUBIC CRYSTALS |
| Uses | Platinum plating; manufacture of spongy platinum. |
| Uses | Ammonium chloroplatinate is used in electroplating of platinum, manufacturing of platinum spongeAmmonium hexachloroplatinate(IV) is used in electroplating of platinum and to make spongy platinum. It reacts with copper(II) acetate and hydrogen sulfide to prepare Cu2PtIIPt3IVS8 which finds application in diamagnetic materials and semiconductors. It is also used in platinum plating. Further, it acts as an analytical reagent. |
| Definition | ChEBI: Ammonium hexachloroplatinate is an ammonium salt comprising separate ammonium cations and octahedral [PtCl6](2-) anions. It contains a hexachloroplatinate(2-). |
| Flammability and Explosibility | Not classified |
| Safety Profile | Poison by inhalation and ingestion. Human pulmonary system effects by inhalation. See also PLATINUM COMPOUNDS. An explosively unstable compound. Incompatible with KOH (boiling with alkali yields a product which, after drying, will explode @ 205' or if mixed with combustibles). When heated to decomposition it emits very toxic fumes of Cl-, NOx, and NH3. |
| Potential Exposure | It is used in photography, platinumplating and in the manufacture of platinum sponge. |
| Shipping | UN3288 Toxic solids, inorganic, n.o.s., HazardClass: 6.1; Labels: 6.1-Poisonous materials, TechnicalName Required. |
| Incompatibilities | Ammonium chloroplatinate is unstable and potentially explosive. Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. |
| Waste Disposal | Because of the high value ofthe metal, recovery is the economically indicated disposalmethod. |
Ammonium chloroplatinate Preparation Products And Raw materials
| Preparation Products | Platinum-->Chloroplantinic acid |
