Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III) CAS 435294-03-4

Introduction：Basic information about Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III) CAS 435294-03-4, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III) Basic information

• Product Name: Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III)
• Synonyms: Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III);Bis(1-phenyl-isoquinoline-C2,N)(acetylacetonato)iridium(III);Ir(piq)2(acac) , Bis(1-phenylisoquinoline)(acetylacetonato)ir;IridiuM (III) bis(1-phenylisoquinolyl-N,C2') acetylacetonate;iridium(III) 4-oxopent-2-en-2-olate bis(2-(isoquinolin-1-yl)benzen-1-ide);Iridium, bis(1-phenyl-isoquinolinato-C2,N) acetylacetonate;(piq)2Ir(acac);Bis[2-(1-isoquinolinyl-N)phenyl-C](2,4-pentanedionato-O2,O4)iridium(III)
• CAS: 435294-03-4
• MF: C35H28IrN2O2-2
• MW: 700.82602
• Product Categories: oled materials;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
• Mol File: 435294-03-4.mol

Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III) Chemical Properties

• Melting point: 366-370°C
• storage temp.: 2-8°C, protect from light, stored under nitrogen
• form: powder or crystals
• color: Red
• λmax: 341 nm in dichloromethane 476 nm in dichloromethane
• InChI: InChI=1S/2C15H10N.C5H8O2.Ir/c2*1-2-7-13(8-3-1)15-14-9-5-4-6-12(14)10-11-16-15;1-4(6)3-5(2)7;/h2*1-7,9-11H;3,6H,1-2H3;/q2*-1;;/b;;4-3-;
• InChIKey: SQMQOSSYPCILHQ-DVACKJPTSA-N
• SMILES: CC(=O)[CH-]C(C)=O.[Ir+](c1ccccc1-c2nccc3ccccc23)c4ccccc4-c5nccc6ccccc56
• Absorption: λmax?302 nm in THF

Safety Information

• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Storage Class: 11 - Combustible Solids

Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III) Usage And Synthesis

Classification

Organometallic complex, Phosphorescent red emitter, Red dopant, OLED and PLED materials, Sublimed materials.

Applications

Bis(1-phenylisoquinoline)(acetylacetonate)iridium(III), Ir(piq)2(acac) is widely used as an efficient phosphorescent red emitter dopant material in PhOLED devices. It was reported that the piq ligand can partially suppress the triplet-triplet annihilation and show short phosphorescent lifetime.

Description

Bis(1-phenylisoquinoline)(acetylacetonate)iridium(III),?Ir(piq)2(acac) is widely used as an efficient phosphorescent red emitter dopant material in PhOLED devices.?It was reported that the piq ligand can?partially?suppress?the triplet-triplet annihilation and show short phosphorescent lifetime [2].

Uses

High efficiency Red Dopant Material for OLED devices. 17 Cd/A current efficiency; 10 lm/W power efficiency; and 8.8% external quantum efficiency can be achieved for devices using this material.