MAGNESIUM METHOXIDE CAS 109-88-6
Introduction：Basic information about MAGNESIUM METHOXIDE CAS 109-88-6, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
MAGNESIUM METHOXIDE Basic information
| Product Name: | MAGNESIUM METHOXIDE |
| Synonyms: | Magnesium methoxide 7-8% in methanol;MAGNESIUM METHOXIDE, CA. 6-10 WT. % SOLU TION IN METHANOL;MAGNESIUM METHYLATE POWDER 7-8% IN METHANOL;MAGNESIUM METHOXIDE POWDER 95%;magnesium methoxide solution;magnesium methanolate;Dimethoxymagnesium;Magnesium bismethoxide |
| CAS: | 109-88-6 |
| MF: | C2H6MgO2 |
| MW: | 86.37 |
| EINECS: | 203-715-8 |
| Product Categories: | Pyrazoles;MagnesiumChemical Synthesis;Micro/Nanoelectronics;Organic Bases;Solution Deposition Precursors;Synthetic Reagents;bc0001 |
| Mol File: | 109-88-6.mol |
MAGNESIUM METHOXIDE Chemical Properties
| density | 0.816 g/mL at 25 °C |
| vapor pressure | 17kPa at 25℃ |
| refractive index | n |
| Fp | 46 °F |
| solubility | Chloroform (Soluble), Methanol (Soluble), Water (Soluble) |
| form | Liquid |
| Specific Gravity | 0.815 |
| Water Solubility | Decomposes in water. |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Exposure limits | ACGIH: TWA 200 ppm; STEL 250 ppm (Skin) OSHA: TWA 200 ppm(260 mg/m3) NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3) |
| Stability: | Hygroscopic, Moisture sensitive |
| InChI | 1S/2CH3O.Mg/c2*1-2;/h2*1H3;/q2*-1;+2 |
| InChIKey | CRGZYKWWYNQGEC-UHFFFAOYSA-N |
| SMILES | CO[Mg]OC |
| LogP | 0.77 at 20℃ |
| CAS DataBase Reference | 109-88-6(CAS DataBase Reference) |
| EPA Substance Registry System | Methanol, magnesium salt (109-88-6) |
Safety Information
| Hazard Codes | F,T |
| Risk Statements | 11-23/24/25-39/23/24/25-36/38 |
| Safety Statements | 16-36/37-45-26 |
| RIDADR | UN 3274 3/PG 2 |
| WGK Germany | 1 |
| TSCA | TSCA listed |
| HazardClass | 3 |
| PackingGroup | II |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral Eye Dam. 1 Flam. Liq. 2 Skin Corr. 1B STOT SE 1 |
| Uses | The use of magnesium methoxide for the deprotection of alkyl esters is described. This mild reagent provides a good method to cleave esters efficiently and more importantly, allows for effective differentiation between two different esters. Dimethyl carbonate is synthesized directly from carbon dioxide and methanol in the presence of magnesium methoxide. 20 mol% DEA additions to magnesium methoxide showed enhanced stability such that a time-dependent change in the sol was not observed in air. Also enhanced the crystallization process. |
| Preparation | Magnesium Methoxide is prepared by addition of small batches of Magnesium metal to anhydrous MeOH.[1] |
| General Description | Magnesium Methoxide is a weakly basic metal alkoxide; forms stable chelates with enolizable carbonyl compounds. |
| Flammability and Explosibility | Flammable |
| reaction suitability | core: magnesium |
| storage | Magnesium Methoxide uses same precautions as for other metal alkoxides (see Potassium t-Butoxide); avoid contact with eyes and clothing; handle and conduct reactions under an inert atmosphere. For critical experiments, it is recommended that the reagent be freshly prepared. Use in a fume hood. |
| References | 1. FF 1969, 2, 255. |
MAGNESIUM METHOXIDE Preparation Products And Raw materials
| Preparation Products | 2-Chlorotrityl chloride-->CLOTRIMAZOLE IMP. A (PHARMEUROPA): (2-CHLOROPHENYL)DIPHENYLMETHANOL |
