Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimeth

Introduction：Basic information about Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimeth, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1) Basic information

• Product Name: Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1)
• Synonyms: Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1);Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1) (ACI);Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-3'-sodiumsulfonato-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),sSPhosPdG2;2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-Palladate(1-) sodium (1:1) (ACI);2'-(Amino-kappan)-biphenyl-2-yl-kappac]chloro[2'-(dicyclohexylphosphino-kappap)-2,6-dimethoxy-biphenyl-3-sulfonato]-palladate(I) sodium;chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl-3'-sulfonato) sodium [2-(2'-amino-1,1'-biphenyl)]palladium(II)
• CAS: 2375242-78-5
• MF: C38H44ClNO5PPdS.Na
• MW: 822.67
• Mol File: 2375242-78-5.mol

Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1) Chemical Properties

• Melting point: 193-194 °C (decomposition)
• storage temp.: 2-8°C, sealed storage, away from moisture
• form: solid
• color: Light brown to brown
• InChIKey: MWQYWXJKMDRSJN-UHFFFAOYSA-L
• SMILES: [Na+].Nc1ccccc1-c2ccccc2[Pd]Cl.COc3ccc(c(OC)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6)S([O-])(=O)=O

Safety Information

• WGK Germany: WGK 3
• Storage Class: 11 - Combustible Solids

Palladate(1-), [2′-(amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[2′-(dicyclohexylphosphino-κP)-2,6-dimethoxy[1,1′-biphenyl]-3-sulfonato]-, sodium (1:1) Usage And Synthesis

Uses

sSPhos Pd G2 can be used as a water-soluble Pd-precatalyst in:

• DNA-compatible Suzuki-Miyaura reaction between DNA-linked aryl halides and various boronic acids/esters including heteroaryl boronates.
• DNA-compatible hydroxycarbonylation reactions.
• The cross-coupling reaction between boronic ester and brominated cyclic nucleotide to synthesize cyclic adenosine and guanosine monophosphate in the presence of potassium phosphate and hydrochloric acid.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings