CAS 32677-01-3|H-Glu(OtBu)-OtBu.HCl

Introduction:Basic information about CAS 32677-01-3|H-Glu(OtBu)-OtBu.HCl, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NameH-Glu(OtBu)-OtBu.HCl
CAS Number32677-01-3Molecular Weight295.803
Density1.02g/cm3Boiling Point311.1ºC at 760 mmHg
Molecular FormulaC13H26ClNO4Melting Point60 to 75ºC
MSDSUSAFlash Point78.1ºC

Names

Nameditert-butyl (2S)-2-aminopentanedioate,hydrochloride
SynonymMore Synonyms

H-Glu(OtBu)-OtBu.HCl BiologicalActivity

DescriptionH-Glu(OtBu)-OtBu hydrochloride is a glutamate derivative that can be used for substance P antagonist synthesis[1].
Related CatalogSignaling Pathways >>Neuronal Signaling >>Neurokinin ReceptorResearch Areas >>Neurological DiseaseSignaling Pathways >>GPCR/G Protein >>Neurokinin Receptor
Target

Substance P[1]

References

[1]. Manolopoulou A, et al. Synthesis of potent antagonists of substance P by modifying the methionyl and glutaminyl residues of its C-terminal hexapeptide and without using D-amino acids. Int J Pept Protein Res. 1993 Apr;41(4):411-4.

Chemical & Physical Properties

Density1.02g/cm3
Boiling Point311.1ºC at 760 mmHg
Melting Point60 to 75ºC
Molecular FormulaC13H26ClNO4
Molecular Weight295.803
Flash Point78.1ºC
Exact Mass295.155029
PSA78.62000
LogP3.27960
InChIKeyLFEYMWCCUAOUKZ-FVGYRXGTSA-N
SMILESCC(C)(C)OC(=O)CCC(N)C(=O)OC(C)(C)C.Cl
Storage condition−20°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MA0880000
CHEMICAL NAME :
L-Glutamic acid, bis(1,1-dimethylethyl)ester, hydrochloride
CAS REGISTRY NUMBER :
32677-01-3
LAST UPDATED :
198703
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C13-H25-N-O4.Cl-H

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
148 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
NTOTDY Neurobehavioral Toxicology and Teratology. (Fayetteville, NY) V.3-8, 1981-86. For publisher information, see NETEEC. Volume(issue)/page/year: 7,275,1985
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
148 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold
REFERENCE :
NTOTDY Neurobehavioral Toxicology and Teratology. (Fayetteville, NY) V.3-8, 1981-86. For publisher information, see NETEEC. Volume(issue)/page/year: 7,275,1985

Safety Information

Personal Protective EquipmentEyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard CodesXi
RIDADRNONH for all modes of transport
WGK Germany3
RTECSMA0880000

Articles3

More Articles
Synthesis and biological activity of analogues of the C-terminal hexapeptide of substance P with modifications at glutaminyl and methioninyl residues. Structure-activity studies.

Int. J. Pept. Protein Res. 40 , 395-400, (1992)

Analogues of [Orn6]-SP6-11 have been synthesized in which the methionyl residue is replaced by glutamine gamma-carboxamide substituted derivatives. These analogues where tested in three in vitro prepa...

Synthesis of potent antagonists of substance P by modifying the methionyl and glutaminyl residues of its C-terminal hexapeptide and without using D-amino acids.

Int. J. Pept. Protein Res. 41 , 411-414, (1993)

Analogues of [Orn6]-SP6-11 have been synthesized in which the Met11-NH2 residue is replaced by the alpha, gamma-dimethyl, alpha, gamma-dibenzyl and alpha, gamma-di-tert-butyl esters of glutamic acid. ...

Convulsant properties of L-glutamic acid di-tert butyl ester.

Neurobehav. Toxicol. Teratol. 7 , 275-278, (1985)

Glutamic acid di-tert butyl ester (GTBE) was found to have a pronounced convulsant effect in mice and rats, producing recurrent clonic convulsions combined with postural and respiratory disturbances i...

Synonyms

H-Glu(OtBu)-OtBu·HCl
H-Glu(OtBu)-OtBu��HCl
L-glutamic acid di-t-butyl ester hydrochloride
MFCD00058003
Di-tert-butyl L-glutamate hydrochloride (1:1)
L-Glutamic acid, bis(1,1-dimethylethyl) ester, hydrochloride (1:1)
H-Glu(OtBu)-OtBu,HCl
H-L-Glu(OtBu)-OtBu*HCl
L-Glutamic acid di-tert
L-Glutamic Acid di-Tert-Butyl Ester Hydrochloride
Bis(2-methyl-2-propanyl) L-glutamate hydrochloride (1:1)
(S)-Di-tert-butyl 2-aminopentanedioate hydrochloride
H-Glu(OtBu)-OtBu.HCl
L-Glutamic acid di-tert-butylester hydrochloride
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