CAS 108-11-2|4-Methylpentan-2-ol
| Common Name | 4-Methylpentan-2-ol | ||
|---|---|---|---|
| CAS Number | 108-11-2 | Molecular Weight | 102.175 |
| Density | 0.8±0.1 g/cm3 | Boiling Point | 133.5±8.0 °C at 760 mmHg |
| Molecular Formula | C6H14O | Melting Point | -90 °C |
| MSDS | ChineseUSA | Flash Point | 41.1±0.0 °C |
| Symbol | GHS02, GHS07 | Signal Word | Warning |
Names
| Name | 4-Methyl-2-pentanol |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 0.8±0.1 g/cm3 |
|---|---|
| Boiling Point | 133.5±8.0 °C at 760 mmHg |
| Melting Point | -90 °C |
| Molecular Formula | C6H14O |
| Molecular Weight | 102.175 |
| Flash Point | 41.1±0.0 °C |
| Exact Mass | 102.104462 |
| PSA | 20.23000 |
| LogP | 1.57 |
| Vapour density | 3.5 (vs air) |
| Vapour Pressure | 3.7±0.5 mmHg at 25°C |
| Index of Refraction | 1.412 |
| InChIKey | WVYWICLMDOOCFB-UHFFFAOYSA-N |
| SMILES | CC(C)CC(C)O |
| Stability | Stable. Flammable. Incompatible with oxidizing agents, acids, acid chlorides. |
| Water Solubility | 2 g/100 mL |
Toxicological Information
CHEMICAL IDENTIFICATION |
ACUTE TOXICITY DATA - TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2590 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 4,119,1951
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2000 ppm/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,343,1949
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1 gm/kg
- TOXIC EFFECTS :
- Gastrointestinal - other changes
- REFERENCE :
- UCPHAQ University of California, Berkeley, Publications in Pharmacology. (Berkeley, CA) V.1-3, 1938-57. Discontinued. Volume(issue)/page/year: 2,217,1949
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 812 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583) Volume(issue)/page/year: -,7,1961
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 3560 uL/kg
- REFERENCE :
- AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 4,119,1951 *** REVIEWS *** ACGIH TLV-STEL 167 mg/m3 (40 ppm) (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 104 mg/m3 (25 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 25 ppm (100 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,166,1971 OSHA PEL (Gen Indu):8H TWA 25 ppm (100 mg/m3) (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 25 ppm (100 mg/m3) (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 25 ppm (100 mg/m3) (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 25 ppm (100 mg/m3) (skin) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 25 ppm (100 mg/m3);STEL 40 ppm;Skin JAN 1993 OEL-BELGIUM:TWA 25 ppm (104 mg/m3);STEL 40 ppm (166 mg/m3);Skin JAN 1993 OEL-DENMARK:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-FINLAND:TWA 25 ppm (100 mg/m3);STEL 40 ppm (170 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-GERMANY:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-RUSSIA:STEL 10 mg/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 25 ppm (100 mg/m3);STEL 125 ppm;Skin JAN 1993 OEL-UNITED KINGDOM:TWA 25 ppm (100 mg/m3);STEL 40 ppm;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO THE CHEMICAL-air:10H TWA 25 ppm (Sk);STEL 40 ppm (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X3241 No. of Facilities: 2585 (estimated) No. of Industries: 31 No. of Occupations: 33 No. of Employees: 26405 (estimated) No. of Female Employees: 2882 (estimated)
Safety Information
| Symbol | GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226-H319-H335 |
| Precautionary Statements | P210-P305 + P351 + P338-P370 + P378 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi:Irritant; |
| Risk Phrases | R10;R37 |
| Safety Phrases | S24/25 |
| RIDADR | UN 2282 3/PG 3 |
| WGK Germany | 1 |
| RTECS | SA7350000 |
| Packaging Group | III |
| Hazard Class | 3 |
| HS Code | 29051900 |
Customs
| HS Code | 2905199090 |
|---|---|
| Summary | 2905199090. saturated monohydric alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |
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Synonyms
| FEMA 3351 |
| 3-HEXYL ALCOHOL |
| EINECS 210-790-0 |
| dimethyl 2-butanol |
| 4-Methyl-2-pentanol |
| (±)-4-Methyl-2-pentanol |
| DL-3-HEXANOL |
| Metilamil alcohol |
| MAOH |
| 2-Pentanol, 4-methyl- |
| Methyl isobutyl carbinol (MIBC) |
| sec-Hexyl Alcohol |
| 1-Ethylbutanol |
| 4-Methylpentan-2-ol |
| pentan-2-ol, 4-methyl- |
| 3-MIC,Isobutyl methyl carbinol,MAOH |
| methyl-isobutyl-carbinol |
| 2-methyl-4-pentanol |
| 3-MIC |
| 1,3-Dimethyl butanol |
| Methyl Isobutyl Carbinol |
| MFCD00004550 |
| 1,3-dimethylbutanol |
| Methylisobutylcarbinol |
| Methyl-2-pentanol |
| isobutylmethylcarbinol |
| UNII:8U34XJK0R0 |
| MIBC |
| 4-methyl-2pentanol |
