CAS 32042-38-9|2,2,2-Trifluoroethyl formate

Introduction：Basic information about CAS 32042-38-9|2,2,2-Trifluoroethyl formate, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Safety Information
4. Customs
5. Articles1
6. Synonyms

Common Name	2,2,2-Trifluoroethyl formate
CAS Number	32042-38-9	Molecular Weight	128.050
Density	1.3±0.1 g/cm3	Boiling Point	33.7±40.0 °C at 760 mmHg
Molecular Formula	C₃H₃F₃O₂	Melting Point	/
MSDS	ChineseUSA	Flash Point	-17.7±19.6 °C
Symbol	GHS02, GHS07	Signal Word	Danger

Names

Name	2,2,2-trifluoroethyl formate
Synonym	More Synonyms

Chemical & Physical Properties

Density	1.3±0.1 g/cm3
Boiling Point	33.7±40.0 °C at 760 mmHg
Molecular Formula	C₃H₃F₃O₂
Molecular Weight	128.050
Flash Point	-17.7±19.6 °C
Exact Mass	128.008514
PSA	26.30000
LogP	1.07
Vapour Pressure	547.2±0.1 mmHg at 25°C
Index of Refraction	1.300
InChIKey	CAFROQYMUICGNO-UHFFFAOYSA-N
SMILES	O=COCC(F)(F)F
Storage condition	Flammables area

Safety Information

Symbol	GHS02, GHS07
Signal Word	Danger
Hazard Statements	H225-H302-H319
Precautionary Statements	P210-P305 + P351 + P338
Personal Protective Equipment	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	F,Xn
Risk Phrases	R11
Safety Phrases	26
RIDADR	UN 1993 3/PG 2
Packaging Group	II
Hazard Class	3.0
HS Code	2915120000

Customs

HS Code	2915120000
Summary	2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles1

2,2,2-trifluoroethyl formate: a versatile and selective reagent for the formylation of alcohols, amines, and N-hydroxylamines.

Org. Lett. 4 , 111, (2002)

[reaction: see text] Treatment of a variety of alcohols, amines, and N-hydroxylamines with 2,2,2-trifluoroethyl formate gave the corresponding formylated adducts in high yields.

Synonyms

Zayia's reagent

HCOOCH2CF3

TFEF

Formic Acid 2,2,2-Trifluoroethyl Ester

Ameisensaeure-2,2,2-trifluorethylester

Ethanol, 2,2,2-trifluoro-, formate

2,2,2-Trifluoroethyl formate

trifluoroethyl formate

2,2,2-trifluoroethylformate

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