Introduction:Basic information about CAS 17041-60-0|Dimethyl 2-ethylidenemalonate, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Novel synthesis of conjugated dienes attached to a quaternary carbon center via Pd(0)-catalyzed deconjugative allylation of alkenylidenemalonates.
J. Org. Chem. 68(25) , 9858-60, (2003)
Palladium(0)-catalyzed deconjugative allylation of alkenylidenemalonates and alkylidenemalonates was achieved for the first time. Reactions of dimethyl 2-((E)-but-2-enylidene)malonate with various all...
Carbon-carbon bond forming reactions of N-bound transition metal a-cyanocarbanions: a mechanistic probe for catalytic Michael reactions of nitriles Naota T, et al.