CAS 2009-97-4|BUTANOIC ACID, 2-DIAZO-3-OXO-, ETHYL ESTER
Introduction：Basic information about CAS 2009-97-4|BUTANOIC ACID, 2-DIAZO-3-OXO-, ETHYL ESTER, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | BUTANOIC ACID, 2-DIAZO-3-OXO-, ETHYL ESTER | ||
|---|---|---|---|
| CAS Number | 2009-97-4 | Molecular Weight | 156.13900 |
| Density | 1.131 g/mL at 25ºC(lit.) | Boiling Point | / |
| Molecular Formula | C6H8N2O3 | Melting Point | / |
| MSDS | ChineseUSA | Flash Point | 185 °F |
| Symbol | GHS07 | Signal Word | Warning |
Names
| Name | Ethyl diazoacetoacetate |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 1.131 g/mL at 25ºC(lit.) |
|---|---|
| Molecular Formula | C6H8N2O3 |
| Molecular Weight | 156.13900 |
| Flash Point | 185 °F |
| Exact Mass | 156.05300 |
| PSA | 80.76000 |
| Index of Refraction | n20/D 1.474(lit.) |
| InChIKey | JWTPSIXYXYNAOU-UHFFFAOYSA-N |
| SMILES | CCOC(=O)C(=[N+]=[N-])C(C)=O |
Safety Information
| Symbol | GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | 36/37/38 |
| Safety Phrases | 26-36 |
| HS Code | 2927000090 |
Customs
| HS Code | 2927000090 |
|---|---|
| Summary | 2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
Articles4
More Articles| A new route to hindered tertiary amines. J. Org. Chem. 66(20) , 6729-33, (2001) The Rh(2)(OAc)(4)-stabilized carbenoid derived from dimethyl diazomalonate has been found to insert into the N-H bond of sterically hindered secondary aliphatic amines to afford hindered tertiary alip... | |
| A simple one-pot preparation of diazoacetoacetate derivatives from aldehydes. J. Org. Chem. 73(21) , 8675-7, (2008) Diazoacetoacetate derivatives can be simply and efficiently prepared from aldehydes in a one-pot process involving initial DBU-promoted "aldol" condensation with ethyl diazoacetate followed by in situ... | |
| Niobium (V) chloride-catalyzed C-H insertion reactions of a-diazoesters: synthesis of ß-keto esters. Yadav JS, et al. Tetrahedron 61(4) , 875-78, (2005) |
Synonyms
| ethyl 2-diazo-3-oxobutanoate |
| ethyl 2-diazo-3-acetoacetate |
| ethyl 2-diazoacetoacetate |
| MFCD09039264 |
| 2-Diazo-3-oxobutyric acid ethyl |
| 2-Diazoacetoacetic acid ethyl ester |
| 2-diazo-3-oxobutyric acid ethyl ester |
| 2-Diazo-3-oxobutanoic acid ethyl ester |
| Butanoic acid,2-diazo-3-oxo-,ethyl ester |
| 3-Oxo-2-diazobutanoic acid ethyl ester |
