CAS 76189-56-5|(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
Introduction：Basic information about CAS 76189-56-5|(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl | ||
|---|---|---|---|
| CAS Number | 76189-56-5 | Molecular Weight | 622.67 |
| Density | / | Boiling Point | 724.3±55.0 °C at 760 mmHg |
| Molecular Formula | C44H32P2 | Melting Point | 239-242ºC |
| MSDS | ChineseUSA | Flash Point | 419.0±37.8 °C |
Names
| Name | (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl |
|---|---|
| Synonym | More Synonyms |
BiologicalActivity
| Description | (S)-BINAP is the inactive isomer of (R)-BINAP (HY-W017757), and can be used as an experimental control. (R)-BINAP is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
|---|---|
| Related Catalog | Research Areas >>OthersSignaling Pathways >>Others >>Others |
| References | [1]. Nathalia Azevedo Portilho, et al. The DNMT1 inhibitor GSK-3484862 mediates global demethylation in murine embryonic stem cells. [2]. Keystone Symposia 2019 - Epigenetics and Human Disease |
Chemical & Physical Properties
| Boiling Point | 724.3±55.0 °C at 760 mmHg |
|---|---|
| Melting Point | 239-242ºC |
| Molecular Formula | C44H32P2 |
| Molecular Weight | 622.67 |
| Flash Point | 419.0±37.8 °C |
| Exact Mass | 622.197937 |
| PSA | 27.18000 |
| LogP | 13.38 |
| Vapour Pressure | 0.0±2.3 mmHg at 25°C |
| Index of Refraction | -235 ° (C=0.3， Toluene) |
Safety Information
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| Hazard Codes | Xi:Irritant |
| Risk Phrases | R36/37/38 |
| Safety Phrases | S26-S37/39 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
Articles11
More Articles| On the mechanism of an asymmetric alpha,beta-unsaturated carboxylic acid hydrogenation: application to the synthesis of a PGD2 receptor antagonist. J. Am. Chem. Soc. 128 , 17063, (2006) Ruthenium complexes employing axially chiral ligands were found to be effective asymmetric hydrogenation catalysts for the reduction of alpha,beta-unsaturated ene acid 1-E to give 2, a prostaglandin D... | |
| The preparation of bi-functional organophosphine oxides as potential antitumor agents. Eur. J. Med. Chem. 45 , 5527-30, (2010) Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylph... | |
| Ohkuma, T. et al. J. Am. Chem. Soc. 117 , 2675, (1995) |
Synonyms
| 2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthalene |
| Phosphine, 1,1'-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenyl- |
| rac-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl |
| 1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane) |
| (±)-BINAP |
| 1,1'-Binaphthalen-2,2'-diylbis(diphenylphosphan) |
| 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) |
| rac-binap |
| UNII:OX12238KWH |
| (r)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl |
| BINAP |
| [1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine] |
| MFCD00010805 |
| UNII:970O8508MB |
| UNII:4F1X2F8NA3 |
