Introduction:Basic information about CAS 6909-30-4|(+)-Trans-limonene1,2-epoxide, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
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Catalytic mechanism of limonene epoxide hydrolase, a theoretical study.
J. Am. Chem. Soc. 127(41) , 14339-47, (2005)
The catalytic mechanism of limonene epoxide hydrolase (LEH) was investigated theoretically using the density functional theory method B3LYP. LEH is part of a novel limonene degradation pathway found i...
QM/MM study of the mechanism of enzymatic limonene 1,2-epoxide hydrolysis.
Biochim. Biophys. Acta 1824(2) , 263-8, (2012)
Limonene 1,2-epoxide hydrolase (LEH) is completely different from those of classic epoxide hydrolases (EHs) which catalyze the hydrolysis of epoxides to vicinal diols. A novel concerted general acid c...
Total synthesis of (+)-cymbodiacetal: a re-evaluation of the biomimetic route.
J. Org. Chem. 75(24) , 8465-70, (2010)
A total synthesis of (+)-cymbodiacetal (1) has been completed from (R)-(+)-limonene oxide using a hetero-Diels-Alder cycloaddition as a key step. The key Diels-Alder cycloaddition proceeds with endo-s...