CAS 246047-72-3|Grubbs Catalyst 2nd Generation

Introduction：Basic information about CAS 246047-72-3|Grubbs Catalyst 2nd Generation, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Safety Information
4. Articles13
5. Synonyms

Common Name	Grubbs Catalyst 2nd Generation
CAS Number	246047-72-3	Molecular Weight	848.971
Density	/	Boiling Point	/
Molecular Formula	C₄₆H₆₅Cl₂N₂PRu	Melting Point	143-149ºC
MSDS	ChineseUSA	Flash Point	/
Symbol	GHS02	Signal Word	Warning

Names

Name	benzylidene-[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichlororuthenium,tricyclohexylphosphane
Synonym	More Synonyms

Chemical & Physical Properties

Melting Point	143-149ºC
Molecular Formula	C₄₆H₆₅Cl₂N₂PRu
Molecular Weight	848.971
Exact Mass	848.330627
PSA	20.07000
LogP	13.86190
InChIKey	FCDPQMAOJARMTG-UHFFFAOYSA-L
SMILES	C1CCC(P(C2CCCCC2)C2CCCCC2)CC1.Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)C2=[Ru](Cl)(Cl)=Cc2ccccc2)c(C)c1
Storage condition	2-8°C

Safety Information

Symbol	GHS02
Signal Word	Warning
Hazard Statements	H228
Precautionary Statements	P210
Personal Protective Equipment	Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes	F
Risk Phrases	36/37/38
Safety Phrases	26-36/37/39
RIDADR	1325
WGK Germany	3
Packaging Group	Ⅱ

Articles13

Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.

Chem. Rev. 110 , 1746, (2010)

Olefin Metathesis and Beyond A list of abbreviations can be found at the end of this article.

Angew. Chem. Int. Ed. Engl. 39 , 3012, (2000)

The advent of well-defined catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups has revolutionized the field. The past decad...

Highly Efficient Ring-Opening Metathesis Polymerization (ROMP) Using New Ruthenium Catalysts Containing N-Heterocyclic Carbene Ligands C.B. is grateful to the National Science Foundation for a pre-doctoral fellowship. The authors thank Dr. Matthias Scholl for providing catalysts 4 a and 4 c.

Angew. Chem. Int. Ed. Engl. 39 , 2903, (2000)

Synonyms

GRUBB'S SECOND GENERATION CATALYST

(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium

[1,3-Bis-(2,4,6-trimethylpheny

MFCD03453237

Grubb's 2nd generation catalyst

Benzylidene(dichloro)(1,3-dimesityl-2-imidazolidinylidene)ruthenium - tricyclohexylphosphine (1:1)

Phosphine, tricyclohexyl-, compd. with [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)ruthenium (1:1)

Grubbs catalyst,2nd Generation

Grubbs 2

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