CAS 6833-84-7|nonactin

Introduction:Basic information about CAS 6833-84-7|nonactin, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Namenonactin
CAS Number6833-84-7Molecular Weight736.92900
Density1.041 g/cm3Boiling Point890.6ºC at 760 mmHg
Molecular FormulaC40H64O12Melting Point147-148°
MSDSChineseUSAFlash Point352.7ºC

Names

NameAmmonium ionophore I
SynonymMore Synonyms

nonactin BiologicalActivity

DescriptionNonactin is a naturally occurring macrotetrolide antibiotic from Streptomyces griseus. Nonactin acts as an ionophore for monovalent cations, including K+, and NH4+[1]. Nonactin is able to uncouple the oxidative phosphorylation of mitochondria. Nonactin selectively induces apoptosis in cell lines harboring active mutant β-catenin[2]. Nonactin inhibits the surface expression of endogenous HSP60[3].
Related CatalogSignaling Pathways >>Apoptosis >>ApoptosisResearch Areas >>CancerResearch Areas >>Infection
References

[1]. Martínez-Haya B, et al. On the ionophoric selectivity of nonactin and related macrotetrolide derivatives. Phys Chem Chem Phys. 2017 Jan 4;19(2):1288-1297.

[2]. Shikata Y, et al. Mitochondrial uncoupler exerts a synthetic lethal effect against β-catenin mutant tumor cells. Cancer Sci. 2017 Apr;108(4):772-784.

[3]. Barazi HO, et al. Identification of heat shock protein 60 as a molecular mediator of alpha 3 beta 1 integrin activation. Cancer Res. 2002 Mar 1;62(5):1541-8.

Chemical & Physical Properties

Density1.041 g/cm3
Boiling Point890.6ºC at 760 mmHg
Melting Point147-148°
Molecular FormulaC40H64O12
Molecular Weight736.92900
Flash Point352.7ºC
Exact Mass736.44000
PSA142.12000
LogP6.02200
Appearance of Characterswhite to faint yellow
Index of Refraction1.452
InChIKeyRMIXHJPMNBXMBU-WRSLMNHTSA-N
SMILESCC1CC2CCC(O2)C(C)C(=O)OC(C)CC2CCC(O2)C(C)C(=O)OC(C)CC2CCC(O2)C(C)C(=O)OC(C)CC2CCC(O2)C(C)C(=O)O1
Storage condition2-8°C
Water Solubilitychloroform: soluble10mg/mL

Safety Information

Personal Protective EquipmentEyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard CodesXi
Safety PhrasesS22-S24/25
RIDADRNONH for all modes of transport
WGK Germany3
RTECSRH1685000
HS Code29321900

Articles33

More Articles
Pilot-plant cultivation of Streptomyces griseus producing homologues of nonactin by precursor-directed biosynthesis and their identification by LC/MS-ESI.

J. Antibiot. 63(8) , 524-9, (2010)

Precursor-directed biogenetic approach was used to produce a range of nonactin homologues in a 50 l fermentor cultivation of strain Streptomyces griseus 34/249 obtained by UV mutagenesis. The producti...

Synthesis of nonactin and the proposed structure of trilactone.

Org. Lett. 8(13) , 2831-4, (2006)

[reaction: see text] An efficient enantioselective route to nonactin using a novel beta-inversion of an Evans syn aldol to construct the THF ring is presented. Through total synthesis, the structure f...

Resolution of methyl nonactate by Rhodococcus erythropolis under aerobic and anaerobic conditions.

Org. Lett. 8(3) , 443-5, (2006)

[reaction: see text]. An efficient resolution of methyl nonactate is reported by biotransformation in shake flask cultures of Rhodococcus erythropolis. The equilibrium of the reaction redox system can...

Synonyms

nonactin
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