CAS 102191-92-4|{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde
Introduction：Basic information about CAS 102191-92-4|{[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | {[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde | ||
|---|---|---|---|
| CAS Number | 102191-92-4 | Molecular Weight | 174.313 |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 161.0±23.0 °C at 760 mmHg |
| Molecular Formula | C8H18O2Si | Melting Point | 165-167ºC |
| MSDS | ChineseUSA | Flash Point | 42.7±18.2 °C |
| Symbol | GHS02, GHS07 | Signal Word | Warning |
Names
| Name | (tert-butyldimethylsilyloxy)acetaldehyde |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 0.9±0.1 g/cm3 |
|---|---|
| Boiling Point | 161.0±23.0 °C at 760 mmHg |
| Melting Point | 165-167ºC |
| Molecular Formula | C8H18O2Si |
| Molecular Weight | 174.313 |
| Flash Point | 42.7±18.2 °C |
| Exact Mass | 174.107605 |
| PSA | 26.30000 |
| LogP | 2.61 |
| Vapour Pressure | 2.3±0.3 mmHg at 25°C |
| Index of Refraction | 1.412 |
| InChIKey | MEBFFOKESLAUSJ-UHFFFAOYSA-N |
| SMILES | CC(C)(C)[Si](C)(C)OCC=O |
| Storage condition | below 5° C |
Safety Information
| Symbol | GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226-H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | S26-S36 |
| RIDADR | UN 1989 |
| WGK Germany | 3 |
| HS Code | 2931900090 |
Customs
| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
Articles6
More Articles| Enantioselective total synthesis of (-)-dactylolide. Org. Lett. 8(6) , 1117-1120, (2006) [reaction: see text] The enantioselective total synthesis of (-)-dactylolide is reported. The absolute stereochemistry of the tetrahydropyran was established by catalytic asymmetric Jacobsen hetero-Di... | |
| One-pot enantioselective syntheses of iminosugar derivatives using organocatalytic anti-michael-anti-aza-Henry reactions. Org. Lett. 12(22) , 5250-3, (2010) Organocatalyst-controlled asymmetric anti-Michael reactions of (tert-butyldimethylsilyloxy)acetaldehyde with a range of nitroolefins, followed by an intermolecular aza-Henry reaction with imine, provi... | |
| Organocatalytic asymmetric assembly reactions for the syntheses of carbohydrate derivatives by intermolecular Michael-Henry reactions. Proc. Natl. Acad. Sci. U. S. A. 107(48) , 20672-7, (2010) Given the significance of carbohydrates in life, medicine, and industry, the development of simple and efficient de novo methods to synthesize carbohydrates are highly desirable. Organocatalytic asymm... |
Synonyms
| MFCD01321229 |
| Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]- |
| 2-[tert-butyl(dimethyl)silyl]oxyacetaldehyde |
| {[Dimethyl(2-methyl-2-propanyl)silyl]oxy}acetaldehyde |
| (tert-Butyldimethylsiloxy)acetaldehyde |
