CAS 69377-81-7|Fluroxypyr

Introduction:Basic information about CAS 69377-81-7|Fluroxypyr, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NameFluroxypyr
CAS Number69377-81-7Molecular Weight255.031
Density1.7±0.1 g/cm3Boiling Point399.4±37.0 °C at 760 mmHg
Molecular FormulaC7H5Cl2FN2O3Melting Point57.5°C
MSDSChineseUSAFlash Point195.3±26.5 °C

Names

Namefluroxypyr
SynonymMore Synonyms

Fluroxypyr BiologicalActivity

DescriptionFluroxypyr is an auxin herbicide to control annual or perennial weeds. Fluroxypyr icauses auxin overdose or excessive endogenous auxin concentrations, thereby resulting in an imbalance of auxin homeostasis and interaction with other hormones in tissues[1].
Related CatalogResearch Areas >>OthersSignaling Pathways >>Others >>Others
References

[1]. Meijun Guo, et al. Comprehensive evaluation of fluroxypyr herbicide on physiological parameters of spring hybrid millet. PeerJ. 2019 Sep 26:7:e7794.  

Chemical & Physical Properties

Density1.7±0.1 g/cm3
Boiling Point399.4±37.0 °C at 760 mmHg
Melting Point57.5°C
Molecular FormulaC7H5Cl2FN2O3
Molecular Weight255.031
Flash Point195.3±26.5 °C
Exact Mass253.966125
PSA85.44000
LogP3.16
Vapour Pressure0.0±1.0 mmHg at 25°C
Index of Refraction1.608
InChIKeyMEFQWPUMEMWTJP-UHFFFAOYSA-N
SMILESNc1c(Cl)c(F)nc(OCC(=O)O)c1Cl

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AF2500000
CHEMICAL NAME :
Acetic acid, ((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-
CAS REGISTRY NUMBER :
69377-81-7
LAST UPDATED :
199412
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C7-H5-Cl2-F-N2-O3
MOLECULAR WEIGHT :
255.04

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2405 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A791,1986
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>296 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCWDF Proceedings of the British Crop Protection Conference - Weeds. (British Crop Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1976- Volume(issue)/page/year: -,939,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 39(235),30,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
458 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCWDF Proceedings of the British Crop Protection Conference - Weeds. (British Crop Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1976- Volume(issue)/page/year: -,939,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PBCWDF Proceedings of the British Crop Protection Conference - Weeds. (British Crop Protection Council, 2A Kidderminster Rd., Croydon, CRO 2UE, UK) 1976- Volume(issue)/page/year: -,939,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A791,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 39(235),30,1985

Safety Information

Hazard StatementsH412
Precautionary StatementsP273
Personal Protective EquipmentEyeshields;Faceshields;Gloves
Risk PhrasesR52/53
Safety PhrasesS61
RIDADRNONH for all modes of transport
RTECSAF2500000
HS Code2942000000

Customs

HS Code2942000000

Articles17

More Articles
Method development for determination of fluroxypyr in water.

J. Environ. Sci. Health B 38(4) , 429-40, (2003)

Improved methods for extraction and clean up of fluroxypyr residue in water have been established. Two methods of fluroxypyr extraction were used, namely, Direct Measurement of fluroxypyr and Concentr...

Determination of starane (fluroxypyr) herbicide using flow injection spectrophotometry.

Anal. Sci. 22(1) , 145-6, (2006)

The starane herbicide was spectrophotometrically determined by the diazotization method in a flow injection assembly. Since starane is a substituted pyridyl compound the NH2 group at the p-position wa...

A pathway-specific microarray analysis highlights the complex and co-ordinated transcriptional networks of the developing grain of field-grown barley.

J. Exp. Bot. 60 , 153-67, (2009)

The aim of the study was to describe the molecular and biochemical interactions associated with amino acid biosynthesis and storage protein accumulation in the developing grains of field-grown barley....

Synonyms

[(4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy]acetic acid
2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic acid
ef-689
4-amino-3,5-dichloro-6-fluoro-pyridin-2-yloxyacetic acid
4-Amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid
[(4-Amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic acid
Acetic acid, [(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]-
4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyaceticacid
MFCD01311822
ff4014
ADVANCE
Fluroxypyr
Acetic acid, 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]-
4,5-amino-3,5-dichloro-6-fluoro-2-pyridinyloxyacetic acid
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