CAS 107-71-1|tert-Butyl peroxyacetate

Introduction:Basic information about CAS 107-71-1|tert-Butyl peroxyacetate, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Nametert-Butyl peroxyacetate
CAS Number107-71-1Molecular Weight132.15800
Density0.828 g/mL at 25 °CBoiling Point122.7ºC at 760 mmHg
Molecular FormulaC6H12O3Melting Point-20 °C
MSDSChineseFlash Point99 °F
Symbol
GHS02, GHS06, GHS08
Signal WordDanger

Names

Nametert-Butyl ethaneperoxoate
SynonymMore Synonyms

Chemical & Physical Properties

Density0.828 g/mL at 25 °C
Boiling Point122.7ºC at 760 mmHg
Melting Point-20 °C
Molecular FormulaC6H12O3
Molecular Weight132.15800
Flash Point99 °F
Exact Mass132.07900
PSA35.53000
LogP1.27960
Vapour Pressure13.8mmHg at 25°C
Index of Refractionn20/D 1.412
InChIKeySWAXTRYEYUTSAP-UHFFFAOYSA-N
SMILESCC(=O)OOC(C)(C)C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SD8925000
CHEMICAL NAME :
Peroxyacetic acid, tert-butyl ester
CAS REGISTRY NUMBER :
107-71-1
BEILSTEIN REFERENCE NO. :
1701510
LAST UPDATED :
199701
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C6-H12-O3
MOLECULAR WEIGHT :
132.18
WISWESSER LINE NOTATION :
1X1&1&OOV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Rinsed with water
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 8,25,1958 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
675 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,30,1982
TYPE OF TEST :
LC33 - Lethal Concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8200 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,30,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
632 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 9,78,1967
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
6000 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 9,78,1967 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1 mg/m3/4H/17W-I
TOXIC EFFECTS :
Behavioral - alteration of operant conditioning Blood - other changes Blood - changes in other cell count (unspecified)
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 10,44,1968 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
1 mg/m3/4H
SEX/DURATION :
male 17 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count)
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 10,44,1968 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-GERMANY JAN 1993 OEL-RUSSIA:STEL 0.1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5363 No. of Facilities: 3 (estimated) No. of Industries: 1 No. of Occupations: 8 No. of Employees: 277 (estimated)

Safety Information

Symbol
GHS02, GHS06, GHS08
Signal WordDanger
Hazard StatementsH226-H242-H302-H304-H315-H319-H331-H335-H340-H350
Precautionary StatementsP201-P210-P280-P304 + P340 + P312-P308 + P313-P370 + P378
Personal Protective EquipmentEyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard CodesT: Toxic;F: Flammable;O: Oxidizing agent;Xi: Irritant;
Risk PhrasesR23/24/25
Safety PhrasesS16-S26-S36/37/39-S45-S62-S47-S14-S7-S53-S3/7
RIDADRUN 3103 5.2
WGK Germany2
RTECSSD8925000
Packaging GroupII
Hazard Class5.2
HS Code2918300090

Customs

HS Code2918300090
Summary2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles1

More Articles

J. Chem. Soc. Perkin Trans. I , 277, (1990)

Synonyms

tert-butyl ethaneperoxoate
MFCD00048240
tert-Butyl peroxyacetate
tert-Butyl peracetate
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