CAS 6226-25-1|2,2,2-Trifluoroethyltrifluoromethanesulfonate

Introduction：Basic information about CAS 6226-25-1|2,2,2-Trifluoroethyltrifluoromethanesulfonate, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Toxicological Information
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
4. Safety Information
5. Customs
6. Articles1
7. Synonyms

Common Name	2,2,2-Trifluoroethyltrifluoromethanesulfonate
CAS Number	6226-25-1	Molecular Weight	232.102
Density	1.7±0.1 g/cm3	Boiling Point	102.8±40.0 °C at 760 mmHg
Molecular Formula	C₃H₂F₆O₃S	Melting Point	/
MSDS	USA	Flash Point	16.0±27.3 °C
Symbol	GHS05, GHS06	Signal Word	Danger

Names

Name	2,2,2-Trifluoroethyl trifluoromethanesulfonate
Synonym	More Synonyms

Chemical & Physical Properties

Density	1.7±0.1 g/cm3
Boiling Point	102.8±40.0 °C at 760 mmHg
Molecular Formula	C₃H₂F₆O₃S
Molecular Weight	232.102
Flash Point	16.0±27.3 °C
Exact Mass	231.962891
PSA	51.75000
LogP	2.26
Vapour Pressure	38.3±0.2 mmHg at 25°C
Index of Refraction	1.317
InChIKey	RTMMSCJWQYWMNK-UHFFFAOYSA-N
SMILES	O=S(=O)(OCC(F)(F)F)C(F)(F)F
Storage condition	2-8°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: PB2775000

CHEMICAL NAME :: Methanesulfonic acid, trifluoro-, 2,2,2-trifluoroethyl ester

CAS REGISTRY NUMBER :: 6226-25-1

LAST UPDATED :: 199806

DATA ITEMS CITED :: 3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530474

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 876 ppm/6H

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - other changes Blood - hemorrhage

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0530474-2

Safety Information

Symbol	GHS05, GHS06
Signal Word	Danger
Hazard Statements	H301-H314-H330
Precautionary Statements	P260-P280-P284-P301 + P310-P305 + P351 + P338-P310
Hazard Codes	Xi: Irritant;T: Toxic;C: Corrosive;
Risk Phrases	36/37/38
Safety Phrases	S26-S36/37/39
RIDADR	UN 3265 8 / PGII
RTECS	PB2775000
HS Code	2905590090

Customs

HS Code	2905590090
Summary	2905590090 other halogenated, sulphonated, nitrated or nitrosated derivatives of acyclic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles1

A general strategy for the synthesis of cyclic N-aryl hydroxamic acids via partial nitro group reduction.

J. Org. Chem. 9th ed., 76 , 3484-3497, (2011)

We describe a generalized approach to stereocontrolled synthesis of substituted cyclic hydroxamic acids (3-amino-1-hydroxy-3,4-dihydroquinolinones) by selective reduction of substituted 2-nitrophenyla...

Synonyms

2,2,2-Trifluoroethyl trifluoromethanesulphonate

2,2,2-Trifluoroethyl triflate

Methanesulfonic acid, 1,1,1-trifluoro-, 2,2,2-trifluoroethyl ester

EINECS 458-390-7

MFCD00671579

2,2,2-Trifluoroethyl trifluoromethanesulfonate

trifluoromethylsulfonyloxy-2,2,2-trifluoroethane

2,2,2-Trifluoroethyltrifluoromethanesulfonate

Methanesulfonic acid,trifluoro-,2,2,2-trifluoroethyl ester

2,2,2-Trifluoroethyl trifluorometanesulfonic acid

Trifluoromethanesulfonic Acid 2,2,2-Trifluoroethyl Ester

trifluoroethyl triflate

2,2,2-TRIFLUOROETHYLTRIFLATE

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