Introduction：Basic information about CAS 32005-36-0|Bis(dibenzylideneacetone)palladium, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | Bis(dibenzylideneacetone)palladium |
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| CAS Number | 32005-36-0 | Molecular Weight | 613.14 |
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| Density | / | Boiling Point | 400.7ºC at 760 mmHg |
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| Molecular Formula | C36H42O2Pd | Melting Point | 150°C |
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| MSDS | ChineseUSA | Flash Point | 176.1ºC |
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Names
| Name | (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium |
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| Synonym | More Synonyms |
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Bis(dibenzylideneacetone)palladium BiologicalActivity
| Description | Bis(dibenzylideneacetone)palladium is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
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| Related Catalog | Research Areas >>Others |
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| In Vitro | 氢化、异构化、羰基化、氧化、CC键形成。Bis(dibenzylideneacetone)palladium(0) 用作制备烯丙基取代的环戊二烯的试剂。它作为均相催化剂以及各种亲核试剂对乙酸烯丙酯的烷基化作用。此外，它还用于铃木反应。 |
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Chemical & Physical Properties
| Boiling Point | 400.7ºC at 760 mmHg |
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| Melting Point | 150°C |
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| Molecular Formula | C36H42O2Pd |
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| Molecular Weight | 613.14 |
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| Flash Point | 176.1ºC |
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| Exact Mass | 574.112427 |
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| PSA | 34.14000 |
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| LogP | 7.96460 |
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| InChIKey | UKSZBOKPHAQOMP-UHFFFAOYSA-N |
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| SMILES | O=C(C=Cc1ccccc1)C=Cc1ccccc1.O=C(C=Cc1ccccc1)C=Cc1ccccc1.[Pd] |
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| Water Solubility | insoluble |
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Safety Information
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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| Hazard Codes | Xi:Irritant |
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| Risk Phrases | R36/38 |
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| Safety Phrases | S22-S24/25-S37/39-S26 |
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| RIDADR | NONH for all modes of transport |
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| WGK Germany | 3 |
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| HS Code | 2914399090 |
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Customs
| HS Code | 2914399090 |
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| Summary | 2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |
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Articles13
More Articles
| Palladium-catalyzed, asymmetric Mizoroki-Heck reaction of benzylic electrophiles using phosphoramidites as chiral ligands. J. Am. Chem. Soc. 134(29) , 11833-5, (2012) We report herein the first examples of asymmetric Mizoroki-Heck reactions using benzyl electrophiles. A new phosphoramidite was identified to be an effective chiral ligand in the palladium-catalyzed r... | |
| Controlling olefin isomerization in the heck reaction with neopentyl phosphine ligands. J. Org. Chem. , (2014) The use of neopentyl phosphine ligands was examined in the coupling of aryl bromides with alkenes. Di-tert-butylneopentylphosphine (DTBNpP) was found to promote Heck couplings with aryl bromides at am... | |
| Sterically bulky thioureas as air- and moisture-stable ligands for pd-catalyzed Heck reactions of aryl halides. Org. Lett. 6 , 1577, (2004) We demonstrate that sterically bulky N,N'-disubstituted cyclic thiourea-Pd(0) complexes are air- and moisture-stable and highly active catalysts for palladium-catalyzed Heck reaction of aryl iodides a... | |
Synonyms
| (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one |
| 1,4-Pentadien-3-one, 1,5-diphenyl-, (1E,4E)-, palladium salt (2:1) |
| Bis(dibenzylideneacetone) palladium(0) |
| (1E,4E)-1,5-Diphenyl-1,4-pentadien-3-one - palladium (2:1) |
| Bis(dibenzylideneacetone)palladium(0) |
| bis-(dibenzylideneacetone)palladium(0) |
| Palladium(0) bis(dibenzylideneacetone) |
| (1E,4E)-1,5-Diphenylpenta-1,4-dien-3-one - palladium (2:1) |
| PD(DBA)2 |
| palladium bis(dibenzylideneacetone) |
| Bis(dibenzylideneacetone)palladium |
| MFCD00051942 |
